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Alborosie
3 years ago
11

At what temperature will 0.100 molal (M) NaCl(aq) boil? Kb= 0.51 C kg mol^-1

Chemistry
1 answer:
Talja [164]3 years ago
7 0
The increase of the boling point of a solution is a colligative property.

The formula for the increase of the normal boiling point of water is:

ΔTb = Kb * m

Where m is the molallity of the solution and Kb is the molal boiling constant in °C/mol.

ΔTb = 0.51 °C / m * 0.100 m = 0.051 °C.

So, the new boiling temperature is Tb = 100°C + 0.051°C = 100.051 °C.

Answer: 100.051 °C
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The formation of SO3 from SO2 and O2 is an intermediate step in the manufacture of sulfuric acid, and it is also responsible for
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118.22 atm

Explanation:

2SO₂(g) + O₂(g) ⇌ 2SO₃(g)      

KP = 0.13 = \frac{p(SO_{3})^{2}}{p(SO_{2})^{2}p(O_{2})}

Where p(SO₃) is the partial pressure of SO₃, p(SO₂) is the partial pressure of SO₂ and p(O₂) is the partial pressure of O₂.

  • With 2.00 mol SO₂ and 2.00 mol O₂ if there was a 100% yield of SO₃, then 2 moles of SO₃ would be produced and 1.00 mol of O₂ would remain.
  • With a 71.0% yield, there are only 2*0.71 = 1.42 mol SO₃, the moles of SO₂ that didn't react would be 2 - 1.42 = 0.58; and the moles of O₂ that didn't react would be 2 - 1.42/2 = 1.29.

The total number of moles is 1.42 + 0.58 + 1.29 = 3.29. With that value we can calculate the molar fraction (X) of each component:

  • XSO₂ = 0.58/3.29 = 0.176
  • XO₂ = 1.29/3.29 = 0.392
  • XSO₃ = 1.42/3.29 = 0.432

The partial pressure of each gas is equal to the total pressure (PT) multiplied by the molar fraction of each component.

  • p(SO₂) = 0.176 * PT
  • p(O₂) = 0.392 * PT
  • p(SO₃) = 0.432 * PT

Rewriting KP and solving for PT:

\frac{p(SO_{3})^{2}}{p(SO_{2})^{2}p(O_{2})}=0.13\\\frac{(0.432*P_{T})^{2}}{(0.176*P_{T})^{2}(0.392*P_{T})} =0.13\\\frac{0.1866*P_{T}^{2}}{0.0121*P_{T}^{3}} =0.13\\\frac{15.369}{P_{T}}=0.13\\P_{T}=118.22 atm

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