The speeds of sound depend upon the temperature of the medium. As the temperature increased in the afternoon, the speed of sound increases. Then the time taken by reflected sound will be less than 0.1 sec in the afternoon. And to hear an echo the time gap between an original sound and reflected sound must be at least 0.1 sec. That is why the student could not hear the echo at all in the afternoon.
Once the car is on top of the hill it contains potentialenergy witch means it is storing enough energy to slide the hill until acted on. Once the car moves and slides down the hill it creates kinetic energy witch means it's in motion. The car then turns the kinetic energy into mechanical energy witch means it's working. I'm not sure if that helped but good luck!