<u>Answer:</u> The expression for equilibrium constant is ![K_{eq}=\frac{[HOCl]^2}{[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%7D%7B%5BH_2O%5D%5BCl_2%5D%5E2%7D)
<u>Explanation:</u>
Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as 
For the general chemical equation:

The expression for
is given as:
![K_c=\frac{[C]^c[D]^d}{[A]^a[B]^b}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BC%5D%5Ec%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%5BB%5D%5Eb%7D)
For the given chemical reaction:

The expression for
is given as:
![K_{eq}=\frac{[HOCl]^2[HgO.HgCl_2]}{[HgO]^2[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%5BHgO.HgCl_2%5D%7D%7B%5BHgO%5D%5E2%5BH_2O%5D%5BCl_2%5D%5E2%7D)
The concentration of solid is taken to be 0.
So, the expression for
is given as:
![K_{eq}=\frac{[HOCl]^2}{[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%7D%7B%5BH_2O%5D%5BCl_2%5D%5E2%7D)
Answer:
36.55kJ/mol
Explanation:
The heat of solution is the change in heat when the KNO3 dissolves in water:
KNO3(aq) → K+(aq) + NO3-(aq)
As the temperature decreases, the reaction is endothermic and the molar heat of solution is positive.
To solve the molar heat we need to find the moles of KNO3 dissolved and the change in heat as follows:
<em>Moles KNO3 -Molar mass: 101.1032g/mol-</em>
10.6g * (1mol/101.1032g) = 0.1048 moles KNO3
<em>Change in heat:</em>
q = m*S*ΔT
<em>Where q is heat in J,</em>
<em>m is the mass of the solution: 10.6g + 251.0g = 261.6g</em>
S is specififc heat of solution: 4.184J/g°C -Assuming is the same than pure water-
And ΔT is change in temperature: 25°C - 21.5°C = 3.5°C
q = 261.6g*4.184J/g°C*3.5°C
q = 3830.87J
<em>Molar heat of solution:</em>
3830.87J/0.1048 moles KNO3 =
36554J/mol =
<h3>36.55kJ/mol</h3>
<em />
In standard notation, the following number would be 86618.5.
According to Boyle's law, volume is inversely proportional to pressure. thus P=k/V
Therefore PV=k
P1V1=P2V2
In the question above,
P1=3.67atm
P2=1.94atm
V1=2.22L
V2=?
Thus substituting for the values in the gas equation;
3.67atm*2.22L=1.94atm*V2
V2=3.67atm*2.22L/1.94atm
=4.21L