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swat32
3 years ago
13

a quantity of zinc reacts with sulfuric acid and produces 0.10g of hydrogen. how many particles of zinc are required socratic.or

g?
Chemistry
1 answer:
alekssr [168]3 years ago
6 0

Answer:

grams of zinc required = 3.24 g

Particles of zinc required = 2.99\times 10^{22}

Explanation:

Given that:-

Mass of hydrogen gas produced = 0.10 g

Calculation of the moles of H_2 as:-

Mass = 0.10 g

Molar mass of H_2 = 2.016 g/mol

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Thus,

Moles= \frac{0.10\ g}{2.016\ g/mol}

Moles= 0.0496\ mol

According to the reaction shown below:-

Zn+H_2SO_4\rightarrow ZnSO_4+H_2

1 mole of hydrogen gas is produced when 1 mole of zinc reacts

So,

0.0496 mole of hydrogen gas is produced when 0.0496 mole of zinc reacts

Moles of Zinc required = 0.0496 moles

Molar mass of zinc = 65.38 g/mol

mass= Moles*Molar mass = 0.0496\ moles\times 65.38\ g/mol=3.24\ g

Also, 1 mole of Zinc contains 6.023\times 10^{23} particles

0.0496 mole of Zinc contains 0.0496\times 6.023\times 10^{23} particles

Particles of zinc required = 2.99\times 10^{22}

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<u>Answer:</u> The rate law for the reaction is \text{Rate}=k'[H+][H_2O_2][Br^-]

<u>Explanation:</u>

Rate law is the expression which is used to express the rate of the reaction in terms of the molar concentration of reactants where each term is raised to the power their stoichiometric coefficient respectively from a balanced chemical equation.

In a mechanism of the reaction, the slow step in the mechanism determines the rate of the reaction.

The chemical equation for the oxidation of bromide ions by hydrogen peroxide in aqueous acid solution follows:

2H^++2Br^-+H_2O_2\rightarrow Br_2+2H_2O

The intermediate reaction of the mechanism follows:

<u>Step 1:</u>  H^++H_2O_2\rightleftharpoons H_3O_2^+;\text{ (fast)}

<u>Step 2:</u>  H_3O_2^++Br^-\rightarrow HOBr+H_2O;\text{(slow)}

<u>Step 3:</u>  HOBr+H^++Br^-\rightarrow Br_2+H_2O;\text{(fast)}

As, step 2 is the slow step. It is the rate determining step

Rate law for the reaction follows:

\text{Rate}=k[H_3O_2^+][Br^-]          ......(1)

As, [H_3O_2^+] is not appearing as a reactant in the overall reaction. So, we apply steady state approximation in it.

Applying steady state approximation for [H_3O_2^+] from step 1, we get:

K=\frac{[H_3O_2^+]}{[H^+][H_2O_2]}  

[H_3O_2^+]=K[H^+][H_2O_2]

Putting the value of [H_3O_2^+] in equation 1, we get:

\text{Rate}=k.K[H^+][H_2O_2][Br^-]\\\\\text{Rate}=k'[H+][H_2O_2][Br^-]

Hence, the rate law for the reaction is \text{Rate}=k'[H+][H_2O_2][Br^-]

4 0
3 years ago
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