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vovangra [49]
3 years ago
13

wo reactions and their equilibrium constants are given. A + 2 B − ⇀ ↽ − 2 C K 1 = 2.57 2 C − ⇀ ↽ − D K 2 = 0.226 A+2B↽−−⇀2CK1=2.

572C↽−−⇀DK2=0.226 Calculate the value of the equilibrium constant for the reaction D − ⇀ ↽ − A + 2 B .
Chemistry
1 answer:
Papessa [141]3 years ago
6 0

<u>Answer:</u> The value of equilibrium constant for the net reaction is 11.37

<u>Explanation:</u>

The given chemical equations follows:

<u>Equation 1:</u>  A+2B\xrightarrow[]{K_1} 2C

<u>Equation 2:</u>  2C\xrightarrow[]{K_2} D

The net equation follows:

D\xrightarrow[]{K} A+2B

As, the net reaction is the result of the addition of first equation and the reverse of second equation. So, the equilibrium constant for the net reaction will be the multiplication of first equilibrium constant and the inverse of second equilibrium constant.

The value of equilibrium constant for net reaction is:

K=K_1\times \frac{1}{K_2}

We are given:

K_1=2.57

K_2=0.226

Putting values in above equation, we get:

K=2.57\times \frac{1}{0.226}=11.37

Hence, the value of equilibrium constant for the net reaction is 11.37

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The question supplied the <em>acid</em> dissociation constant pK_afor acetic acid \text{HAc}; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant pK_b for its conjugate base, \text{Ac}^{-}. The following relationship relates the two quantities:

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