So in this problem, your limiting reactant is the 5.00 mol of Zn, because you have an excess of hydrochloric acid.
The first step to answering this problem is to set up a balanced equation. You start with Zn + HCl ⇒ ZnCl +H In order to balance it, you have to know that Zinc is a +2 ion, Cl is a -1 ion, and H is a +1 ion. Each molecule must be balanced (meaning ionic charges equal to zero), as well as the number of each element on either side of the reaction. This gives you Zn + 2HCl ⇒ ZnCl₂ + 2H Now, in order to find how much Hydrogen gas you have, you have to know how many atoms of Zn you have. 1 mol is 6.022 × 10²⁴ atoms (Avogadro's Number), so if you have 5 mol of Zn, you have 3.011 × 10²⁵ atoms of zinc. Plug this into the reaction and re-balance the formula. (3.011 × 10²⁵ Zn) + (6.022 × 10²⁵ HCl) ⇒ (3.011 × 10²⁵ ZnCl₂) + (6.022 × 10²⁵ H)
You end up with (6.022 × 10²⁵ H), or 10.00 mol H (g)