Mass spectrum of Dodecane will give following information.
1 ) Molecular Peak or Parent Peak:
The Parent peak will appear at m/z = 170. The intensity of this peak will be very weak.
2) Fragments:
Usually the fragments of such long chain alkanes appear with spacing of 14 amu, Hence, the peaks in dodecane will be as follow,
170 - 156 - 142 - 128 - 114 - 100 - 86 - 72 - 58 - 44 - 30 - 16
3) Base Peak:
Most probably the Base peak will appear at m/z = 57. This peak is due to the formation of tertiary butyl cation as the intensity mainly depends upon the stability of cation. So this cation might form due to rearrangment giving the intensity of 100%.
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Answer:
4
Explanation:
1 is correct
Liquids have no definite shape as they take up the shape of the container. Thus, we can say a liquid has no shape of its own but rather has the shape of the container in which it is filled.
2 is correct
When the atmospheric temperature is increased, it also will increase the boiling point of the liquid
3 is correct
This is an extension of the statement 2. While we decrease the atmospheric pressure, we are also decreasing the boiling point
4 is incorrect
A liquid have a definite volume. When we say a volume is definite, it means the volume is fixed and does not change. The volume of liquids is definite for a particular mass of the liquid and does not change
We are given the pOH of the solution of 10.75. pOH is the property of the solution that is related to the OH ion concentration of the solution. THe formula to be followed is pOH = -log (OH); OH- = 10^-pOH. In this case, OH- = 10^-10.75 equal to B. 1.778 x 10^-11 M
