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alexandr402 [8]
3 years ago
13

2NO + 2H2 ⟶N2 + 2H2O What would the rate law be if the mechanism for this reaction were: 2NO + H2 ⟶N2 + H2O2 (slow) H2O2 + H2 ⟶2

H2O (fast)
Chemistry
1 answer:
Talja [164]3 years ago
6 0

Answer:

rate = [NO]²[H₂]

Explanation:

2NO + H2 ⟶N2 + H2O2 (slow)

H2O2 + H2 ⟶2H2O (fast)

From the question, we are given two equations.

In chemical kinetics; that is the study of rate reactions and changes in concentration. The rate law is obtained from the slowest reaction.

This means that our focus would be on the slow reaction. Generally the rate law is obtained from the concentrations of reactants in a reaction.

This means our rate law is;

rate = [NO]²[H₂]

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A sample of limestone (calcium carbonate, CaCO3) is heated at 950 K until it is completely converted to calcium oxide (CaO) and
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Answer:

Therefore, volume of CO₂ produced in the first step is 9141.404 L

Explanation:

Equations of reactions:

A: CaCO₃(s) ---> CaO(s) + CO₂(g)

B: CaO(l) + H₂O(l) ---> Ca(OH)₂(s)

Molar mass of CaCO₃ = 100 g; molar mass of CaO = 56 g; molar mass of CO₂ = 44 g molar mass of H₂P = 18 g; molar mass of Ca(OH)₂ = 74 g

From equation B, 1 mole of CaO produces 1 mole of Ca(OH)₂

This means that 56 g of CaO produces 74 g of Ca(OH)₂

mass of CaO that produces 8.47 kg or 8470 g of Ca(OH)₂ = 8470 g * 56/74 = 6409.73 g of CaO

Therefore, 6409.73 g of CaO were produced in reaction A

From reaction A, 1 mole of CaCO₃ produces 1 mole CaO and 1 mole of CO₂

Number of moles of CaO in 6409.73 g = 6409.73 g/56 g/mol = 114.46 moles

Therefore, 114.46 moles of CO₂ were produces as well.

Molar volume of gas at STP = 22.4 litres

Volume of CO₂ produced at STP = 114.46 * 22.4 L =2563.904 L

However, the above reaction took place at 950 K and 0.976 atm, therefore volume of CO₂ produced under these conditions are obtained using the general gas equation

Using P₁V₁/T₁ = P₂V₂/T₂

P₁ = 1.0 atm, V₁ = 2563.904 L, T₁ = 273 K, P₂ = 0.976 atm, T₂ = 950 K, V₂ = ?

V₂ = P₁V₁T₂/P₂T₁

V₂ = (1.0 * 2563.904 * 950)/(0.976 * 273)

V₂ = 9141.404 L

Therefore, volume of CO₂ produced in the first step is 9141.404 L

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