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alexandr402 [8]
3 years ago
13

2NO + 2H2 ⟶N2 + 2H2O What would the rate law be if the mechanism for this reaction were: 2NO + H2 ⟶N2 + H2O2 (slow) H2O2 + H2 ⟶2

H2O (fast)
Chemistry
1 answer:
Talja [164]3 years ago
6 0

Answer:

rate = [NO]²[H₂]

Explanation:

2NO + H2 ⟶N2 + H2O2 (slow)

H2O2 + H2 ⟶2H2O (fast)

From the question, we are given two equations.

In chemical kinetics; that is the study of rate reactions and changes in concentration. The rate law is obtained from the slowest reaction.

This means that our focus would be on the slow reaction. Generally the rate law is obtained from the concentrations of reactants in a reaction.

This means our rate law is;

rate = [NO]²[H₂]

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7. How many liters of NH3, at STP will react with 10.6 g O2 to form NO2 and water? 4NH3(g) + 7O2(g) → 4NO2(g) + 6H2O(g) *
Alexus [3.1K]

7) Answer is: c. 4.24 L.

Balanced chemical reaction: 4NH₃(g) + 7O₂(g) → 4NO₂(g) + 6H₂O(g).

m(O₂) = 10.6 g; mass of oxygen.

n(O₂) = m(O₂) ÷ M(O₂).

n(O₂) = 10.6 g ÷ 32 g/mol.

n(O₂) = 0.33 mol; amount of oxygen.

Vm = 22.4 L/mol; molar volume at STP (Standard Temperature and Pressure).

At STP one mole of gas occupies 22.4 liters of volume.

V(O₂) = n(O₂) · Vm.

V(O₂) = 0.33 mol · 22.4 L/mol.

V(O₂) = 7.42 L; volume of oxygen.

From balanced chemical reaction: n(O₂) : n(NH₃) = 7 : 4.

n(NH₃) = 4 · 0.33 mol ÷ 7.

n(NH₃) = 0.188 mol; amount of ammonia.

V(NH₃) = 0.188 mol · 22.4 L/mol.

V(NH₃) = 4.24 L.

8) Answer is: a. 3.7 g.

Balanced chemical reaction: P₄(g) + 6H₂(g) → 4PH₃(g).

m(P₄) = 3.4 g; mass of phosphorous.

n(P₄) = m(P₄) ÷ M(P₄).

n(P₄) = 3.4 g ÷ 123.9 g/mol.

n(P₄) = 0.0274 mol; limiting reactant.

n(H₂) = 4 g ÷ 2 g/mol.

n(H₂) = 2 mol; amount of hydrogen.

From balanced chemical reaction: n(P₄) : n(PH₃) = 1 : 4.

n(PH₃) = 4 · 0.0274 mol.

n(PH₃) = 0.1096 mol.

m(PH₃) = 0.1096 mol · 34 g/mol.

m(PH₃) = 3.726 g.

9) Answer is: d. Percent yield is the ratio of theoretical yield to actual yield expressed as a percent.

Percent yield = actual yield / theoretical yield.

Theoretical yield is the maximum amount of product that can be produced from limiting reactant and actual yield is a product that is obtained by experimentation.

For example:

the percent yield = 250 g ÷ 294.24 g · 100%.

the percent yield = 84.5 %.

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