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3 years ago

Draw the addition product formed when one equivalent of hcl reacts with the following diene.

Chemistry

1 answer:

pashok25 [27]3 years ago

5 0

Answer:

Major Product = 4-chloro-4-methylcyclohex-1-ene

Explanation:

Alkene are the class of organic compounds which contain one or more double bonds between two carbon atoms. Alkenes are considered most reactive among the unsaturated hydrocarbons and they undergo addition reactions due to high electron density around the double bonds.

In given question it is written that we are provided with one equivalent of HCl while, our compound contains two double bonds (diene) so in selected starting material the HCl will be added across (hydrohalogenation reaction) the substituted double bond because it will give a more stable carbocation (tertiary carbocation) during the reaction course. Hence, as shown in reaction scheme 4-chloro-4-methylcyclohex-1-ene will be the major product.

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Match the formula for the following compound:

tester [92]

valence of magnesium is 2

and valence of sulfate-ion is 2 too

answer: MgSO4•7H2O

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3 years ago

Read 2 more answers

For the cells in a human body, an isotonic solution is 0.9% NaCl. If a red blood cell is placed in a 1% NaCl solution, what will

igomit [66]

Answer: The red blood cell will shrink due to water loss

Explanation:

Because 1% NaCl solution is slightly more concentrated than its isotonic 0.9% form, the red blood cell will lose its cell containing fluids such as water to the MORE concentrated environment.

This water loss after a prolonged period will result in shrinking of the red blood cell.

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3 years ago

The irreversible elementary gas-phase reaction is carried out isothermally at 305 K in a packed-bed reactor with 100 kg of catal

tamaranim1 [39]

Answer:

0.856.

Explanation:

Lets represent the irreversible elementary gas phase equation of reaction as

A + B -----------------------------------> C + D

We have that the percentage of conversion is 80%.

The pressure, p from the ratio of exit pressure and entering pressure is p = 2/20 = 1/10 = 0.1.

Therefore, n = 1 - p^2/ weight of the catalyst = 1 - 0.1^2/ 100 = 9.9 × 10^-3 kg cat^-.

Now, let's make use of the equation below;

J/ 1 - J = kb^2/ u [ w - nw^2/2] ----------(1).

0.8 / 1- 0.8 = k ( 0.4)^2/ 10 [ 100 - (9.9× 10^-3 × 100^2/ 2] .

k = 4.95 dm^6/ kg.cat .mol.min

The turbulent flow= 1/2 × 9.9 × 10^-3 = 4.95 × 10^-3 kg cat^-.

Thus, making use of the equation (1) again, we have that;

{4.95 × 10^-3 × 0.4}/ 10 × [ 100 - (4.95 × 10^-3 × 100^2)] / 2 = 5.964.

Therefore, a/1 - a = 5.964.

5.964( 1 - a) = a.

5.964 - 5.964a = a.

5.964 = a + 5.964a.

5.964 = 6.964a.

a = 5.964/ 6.964 = 0.856.

5 0

3 years ago

Consider the titration of a 20.0-mL sample of 0.105 M HC2H3O2 with 0.125 M NaOH. Determine each quantity. a. the initial pH b. t

Oksi-84 [34.3K]

Answer:

Explanation:

Given that:

Concentration of $HC_2H_3O_2 \ (M_1)$ = 0.105 M

Volume of $HC_2H_3O_2 \ (V_1)$ = 20.0 mL

Concentration of $NaOH (M_2)$ = 0.125 M

The chemical reaction can be expressed as:

$HC_2H_3O_2_{(aq)} + NaOH _{(aq)} \to NaC_2H_3O_2_{(aq)} + H_2O_{(l)}$

Using the ICE Table to determine the equilibrium concentrations.

$HC_2 H_3 O_2 _{(aq)} + H_2O _{(l) } \to C_2 H_3O_2^- _{(aq)} + H_3O^+_{ (aq)}$

I 0.105 0 0

C -x +x +x

E 0.105 - x x x

$K_a = \dfrac{[C_2H_5O^-_2][H_3O^+]}{[HC_2H_3O_2]}$

$K_a = \dfrac{(x)(x)}{(0.105-x)}$

Recall that the ka for $HC_2H_3O_2= 1.8 \times 10^{-5}$

Then;

$1.8 \times 10^{-5} = \dfrac{(x)(x)}{(0.105 -x)}$

$1.8 \times 10^{-5} = \dfrac{x^2}{(0.105 -x)}$

By solving the above mathematical expression;

x = 0.00137 M

$H_3O^+ = x = 0.00137 \ M \\ \\ pH = - log [H_3O^+] \\ \\ pH = - log ( 0.00137 )$

pH = 2.86

Hence, the initial pH = 2.86

b) To determine the volume of the added base needed to reach the equivalence point by using the formula:

$M_1 V_1 = M_2 V_2$

$V_2= \dfrac{M_1V_1}{M_2}$

$V_2= \dfrac{0.105 \ M \times 20.0 \ mL }{0.125 \ M}$

$V_2 = 16.8 mL$

Thus, the volume of the added base needed to reach the equivalence point = 16.8 mL

c) when pH of 5.0 mL of the base is added.

The Initial moles of $HC_2H_3O_2 =$ molarity × volume

$= 0.105 \ M \times 20.0 \times 10^{-3} \ L$

$= 2.1 \times 10^{-3}$

number of moles of 5.0 NaOH = molarity × volume

number of moles of 5.0 NaOH = $0.625 \times 10^{-3}$

After reacting with 5.0 mL NaOH, the number of moles is as follows:

$HC_2 H_3 O_2 _{(aq)} + NaOH _{(aq)} \to NaC_2H_3O_2_{(aq)} + H_2O{ (l)}$

Initial moles $2.1*10^{-3}$ $0.625 * 10^{-3}$ 0 0

F(moles) $(2.1*10^{-3} - 0.625 \times 10^{-3})$ 0 $0.625 \times 10^{-3}$ $0.625 \times 10^{-3}$

The pH of the solution is then calculated as follows:

$pH = pKa + log \dfrac{[base]} {[acid]}$

Recall that:

pKa for $HC_2H_3O_2=4.74$

Then; we replace the concentration with the number of moles since the volume of acid and base are equal

∴

$pH = 4.74 + log \dfrac{0.625 \times 10^{-3}}{1.475 \times 10^{-3}}$

pH = 4.37

Thus, the pH of the solution after the addition of 5.0 mL of NaOH = 4.37

We need to understand that the pH at 1/2 of the equivalence point is equal to the concentration of the base and the acid.

Therefore;

pH = pKa = 4.74

e) pH at the equivalence point.

Here, the pH of the solution is the result of the reaction in the $(C_2H_3O^-_2)$ with $H_2O$

The total volume(V) of the solution = V(acid) + V(of the base added to reach equivalence point)

The total volume(V) of the solution = 20.0 mL + 16.8 mL

The total volume(V) of the solution = 36.8 mL

Concentration of $(C_2H_3O^-_2)$ = moles/volume

= $\dfrac{2.1 \times 10^{-3} \ moles}{0.0368 \ L}$

= 0.0571 M

Now, using the ICE table to determine the concentration of $H_3O^+$ ;

$C_2H_5O^-_2 _{(aq)} + H_2O_{(l)} \to HC_2H_3O_2_{(aq)} + OH^-_{(aq)}$

I 0.0571 0 0

C -x +x +x

E 0.0571 - x x x

Recall that the Ka for $HC_2H_3O_2$ = $1.8 \times 10^{-5}$

$K_b = \dfrac{K_w}{K_a} = \dfrac{1.0\times 10^{-14}}{1.8 \times 10^{-5} } \\ \\ K_b = 5.6 \times 10^{-10}$

$k_b = \dfrac{[ HC_2H_3O_2] [OH^-]}{[C_2H_3O^-_2]}$

$5.6 \times 10^{-10} = \dfrac{x *x }{0.0571 -x}$

$x = [OH^-] = 5.6 \times 10^{-6} \ M$

$[H_3O^+] = \dfrac{1.0 \times 10^{-14} }{5.6 \times 10^{-6} }$

$[H_3O^+] =1.77 \times 10^{-9}$

$pH =-log [H_3O^+] \\ \\ pH =-log (1.77 \times 10^{-9}) \\ \\ \mathbf{pH = 8.75 }$

Hence, the pH of the solution at equivalence point = 8.75

f) The pH after 5.09 mL base is added beyond (E) point.

$HC_2 H_3 O_2 _{(aq)} + NaOH _{(aq)} \to NaC_2H_3O_2_{(aq)} + H_2O{ (l)}$

Before 0.0021 0.002725 0

After 0 0.000625 0.0021

$[OH^-] = \dfrac{0.000625 \ moles}{(0.02 + 0.0218 ) \ L}$

$[OH^-] = \dfrac{0.000625 \ moles}{0.0418 \ L}$

$[OH^-] = 0.0149 \ M$

From above; we can determine the concentration of $H_3O^+$ by using the following method:

$[H_3O^+] = \dfrac{1.0 \times 10^{-14} }{0.0149}$

$[H_3O^+] = 6.7 \times 10^{-13}$

$pH = - log [H_3O^+]$

$pH = -log (6.7 \times 10^{-13} )$

pH = 12.17

Finally, the pH of the solution after adding 5.0 mL of NaOH beyond (E) point = 12.17

3 0

3 years ago

Approximately 30% of the earth’s fresh water is stored in– A lakes. B streams. C groundwater. D living things.

kirill115 [55]

C ground water hope this is helpful

7 0

3 years ago