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puteri [66]
3 years ago
12

Diffusion of Ammonia in an Aqueous Solution Ammonia (A)-water (B) solution ta 278 K and 4 mm thick is in contact with an organic

liquid at this interface. The concentration of ammonia in the organic phase is held constant and is such that the equilibrium concentration of ammonia at the interface is 2.0 wt% ammonia (density of aqueous solution is 991.7 Kg/m) The concentration of ammonia in water 4 mm away is 10 wt% (density of solution is 961.7 Kg/m). Water and the organic phase are insoluble in each other. The diffusion coefficient of NH3 in water is 1.24 × 10-9 m2/s.
(a) At steady state, calculate Na in Kmol/m-s

(b) Calculate NB. Explain.

Engineering
1 answer:
Tom [10]3 years ago
4 0

Answer:

Explanation:

The pictures below shows the whole explanation for the problem

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A steel bar is 150 mm square and has a hot-rolled finish. It will be used in a fully reversed bending application. Sut for the s
Xelga [282]

Answer:

See explanation

Explanation:

Given The bar is square and has a hot-rolled finish. The loading is fully reversed bending.

Tensile Strength

Sut: 600 MPa

Maximum temperature

Tmax: 500 °C

Bar side dimension

b: 150 mm

Alternating stress

σa: 100 MPa

Reliability

R: 0.999 Note 1.

Assumptions Infinite life is required and is obtainable since this ductile steel will have an endurance limit. A reliability factor of 99.9% will be used.

Solution See Excel file Ex06-01.xls.

1 Since no endurance-limit or fatigue strength information is given, we will estimate S'e based on the ultimate tensile strength using equation 6.5a.

S'e: 300 MPa = 0.5 * Sut

2 The loading is bending so the load factor from equation 6.7a is

Cload: 1

3 The part size is greater than the test specimen and the part is not round, so an equivalent diameter based on its 95% stressed area must be determined and used to find the size factor. For a rectangular section in nonrotating bending, the A95 area is defined in Figure 6-25c and the equivalent diameter is found from equation 6.7d

A95: 1125 mm2 = 0.05 * b * b Note 2.

dequiv: 121.2 mm = SQRT(A95val / 0.0766)

and the size factor is found for this equivalent diameter from equation 6.7b, to be

Csize: 0.747 = 1.189 * dequiv^-0.097

4 The surface factor is found from equation 6.7e and the data in Table 6-3 for the specified hot-rolled finish.

Table 6-3 constants

A: 57.7

b: -0.718 Note 3.

Csurf: 0.584 = Acoeff * Sut^bCoeff

5 The temperature factor is found from equation 6.7f :

Ctemp: 0.710 = 1 - 0.0058 * (Tmax - 450)

6 The reliability factor is taken from Table 6-4 for R = 0.999 and is

Creliab: 0.753

7 The corrected endurance limit Se can now be calculated from equation 6.6:

Se: 69.94 MPa = Cload * Csize * Csurf * Ctemp *

Creliab * Sprme

Let

Se: 70 MPa

8 To create the S-N diagram, we also need a value for the estimated strength Sm at 103 cycles based on equation 6.9 for bending loading.

Sm: 540 MPa = 0.9 * Sut

9 The estimated S-N diagram is shown in Figure 6-34 with the above values of Sm and Se. The expressions of the two lines are found from equations 6.10a through 6.10c assuming that Se begins at 106 cycles.

b: -0.2958 Note 4.

a: 4165.7

Plotting Sn as a function of N from equation 6.10a

N Sn (MPa)

1000 540 =aa*B73^bb

2000 440

4000 358

8000 292

16000 238

32000 194

64000 158

128000 129

256000 105

512000 85

1000000 70

FIGURE 6-34. S-N Diagram and Alternating Stress Line Showing Failure Point

10 The number of cycles of life for any alternating stress level can now be found from equation 6.10a by replacing σa for Sn.

At N = 103 cycles,

Sn3: 540 MPa = aa * 1000^bb

At N = 106 cycles,

Sn6: 70 MPa = aa * 1000000^bb

The figure above shows the intersection of the alternating stress line (σa = 100 MPa) with the failure line at N = 3.0 x 105 cycles.

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