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Orlov [11]
3 years ago
9

Arrhenius acids are 1. substances that produce hydrogen atoms in solution. 2. substances that produce hydronium ions in aqueous

solution. 3. substances that produce hydroxide ions in solution. 4. substances that cause the pH of a solution to increase
Chemistry
1 answer:
ElenaW [278]3 years ago
7 0

Answer:

<h2>1 ) substances that produce hydrogen atoms in solution.</h2>

Explanation:

A swedist scientist Savante Arhenius give the theory of behaviour of Acid-bases. According to Arhenius ,Arhenius Acid compound produce hydrogen ion or proton upon adding in aqueous solution . Acid are molecular compound that have higly polar covalently bonded  ionizable hydrogen atom. HCL is a polar covalently bonded and gas at room temperature and noormal pressure . Upon addition of HCL in water cause ionization ,water breaks into chloride ion and hydrogen ion , in this reaction chlorine gain bond pair electron , while hydrogen ion or proton attached with water . chlorine gain bond pair electron due higher electronegativity than hydrogen and hydrogen loose their electron due to less electronegativity and become hydrogen ion ,these hydrogen ion attached with water to form hydronium ion H_{3}O^{+}(aq) . Hydronium ion is polyatomic ion .

  • Ionization of HCL in water  

         HCL(gas)\rightarrow H^{+}(aq) + CL^{-}(aq)

  •  formation of polyatomic hydronium ion after HCL ionization in water ,where hydrogen ion attached to water and form polyatomic ion.

                 HCL(gas) + H_{2}O(liq)\rightarrow  H_{3}O^{+}(aq) + CL^{-}(aq).

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Hence;

Total number of bread and cheese = 33 + 15.

Each loaf should have two pieces of each bread and the cheeses make a total of four pieces.

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Answer:

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A chemistry student weighs out of sulfurous acid , a diprotic acid, into a volumetric flask and dilutes to the mark with distill
nadezda [96]

The question is incomplete, here is the complete question:

A chemistry student weighs out 0.104 g of sulfurous acid, a diprotic acid, into a 250.0 mL volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with 0.0700 M NaOH solution. Calculate the volume of NaOH solution the student will need to add to reach the final equivalence point. Be sure your answer has the correct number of significant digits.

<u>Answer:</u> The volume of NaOH needed is 36.2 mL

<u>Explanation:</u>

To calculate the molarity of solution, we use the equation:

\text{Molarity of the solution}=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}

Given mass of sulfurous acid = 0.104 g

Molar mass of sulfurous acid = 82 g/mol

Volume of solution = 250 mL

Putting values in above equation, we get:

\text{Molarity of sulfurous acid}=\frac{0.104\times 1000}{82\times 250}\\\\\text{Molarity of sulfurous acid}=5.07\times 10^{-3}M

To calculate the volume of base, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is H_2SO_3

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=2\\M_1=5.07\times 10^{-3}M\\V_1=250mL\\n_2=1\\M_2=0.0700M\\V_2=?mL

Putting values in above equation, we get:

2\times 5.07\times 10^{-3}\times 250.0=1\times 0.0700\times V_2\\\\V_2=\frac{2\times 5.07\times 10^{-3}\times 250}{1\times 0.0700}=36.2mL

Hence, the volume of NaOH needed is 36.2 mL

5 0
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Calculate the pH of each of the following solutions: (a) 0.1000M Propanoic acid (HC3H5O2, Ka= 1.3x10-5 ) (b) 0.1000M sodium prop
jek_recluse [69]

(a) The pH of 0.1000 M propanoic acid (HC3H5O2) is 2.9.

(b) The pH of 0.1000 M sodium propanoate (NaC3H5O2) is 8.9.

(c) The pH of 0.1000 M propanoic acid (HC3H5O2) and 0.1000 M sodium propanoate (NaC3H5O2) is 4.9.

<h3>Further explanation:</h3>

(a)

Given information:

The value of acid ionization constant for propanoic acid is  1.3 x 10^{-5} .

The initial concentration of propanoic acid is  .

To calculate:

The pH of 0.1000 M propanoic acid solution.

Solution:

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

 

The expression for acid dissociation constant is,

                                                            …… (1)

Here,

 is ionization constant of propanoic acid.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydronium ion.

 is the equilibrium concentration of propanoic acid.

ICE table (1):

 

Refer ICE table (1),

 

Substitute the values form the ICE table (1) in equation (1).

 

The approximation x is very small is valid. Therefore, the value of x can be neglected. Above equation can be modified as,

 

Rearrange above equation for x.

                                                                                                           …… (2)

Substitute   for   in equation (2) to calculate the value of x.

 

Therefore, from the ICE table (1) the concentration of hydronium ion is,

 .

The negative logarithm of hydronium ion concentration is defined as the pH of the solution. Mathematically,

                                                                                                               …… (3)

Substitute    for    in equation (3) to calculate the pH of the solution.

 

(b)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate solution.

Solution:

Sodium propanoate  is conjugate base of weak propanoic acid. It undergoes hydrolysis in water to yield hydroxide ion in the solution as follows:

                                                        …… (4)

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

                                                       …… (5)

Dissociation reaction for water is written as follows:

                                                                                       …… (6)

From equation (4), (5), and (6) the relationship between   and   is,

                                                                                                                              …… (7)

Substitute   for   and   for   in equation (7).

 

ICE table (2):

 

The expression for base dissociation constant is,

                                                                                                     …… (8)

Here,

is base ionization constant.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydroxide ion.

 is the equilibrium concentration of propanoic acid.

From the ICE table (2),

 

Substitute the values form the ICE table (2) in equation (8).

 

The approximation y is very small is valid. Therefore, the value of y can be neglected. Above equation can be modified as,

 

Rearrange above equation for y.

                                                                                                           …… (9)

Substitute   for   in equation (9) to calculate the value of y.

 

Therefore, from the ICE table (2) the concentration of hydroxide ion is,

 

The negative logarithm of hydroxide ion concentration is defined as pOH of the solution. Mathematically,

                                                                                                           …… (10)

Substitute    for    in equation (10) to calculate pOH of the solution.

 

The relation between pH and pOH is as follows:

                                                                                                                   …… (11)

Substitute 5.057 for pOH in equation (11) to calculate the pH of the solution.

 

(c)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate and 0.1000 M propanoic acid solution.

Solution:

Propanoic acid is a weak acid, and sodium propanoate is salt of the conjugate base of propanoic acid. Thus, propanoic acid and sodium propanoate will form a buffer system.

The pH of the buffer solution can be determined with the help of the Henderson-Hasselbalch equation. Mathematically,

 

For propanoic acid and sodium propanoate buffer system, the Henderson-Hasselbalch equation can be modified as,

                                                                                               …… (12)

The negative logarithm of acid ionization constant is equal to  .

                                                                                                                …… (13)

Substitute   for  in equation (13).

 

Substitute    for  ,   for   and 4.9 for    in equation (12).

 

Learn more:

1. About Henderson-Hasselbalch equation brainly.com/question/12999557

2. Learn more about how to calculate moles of the base in given volume brainly.com/question/4283309

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Ionic equilibria

Keywords: ionic equilibrium, propanoic acid, sodium propanoate, ionization constant, weak acid, conjugate base, equilibrium concentration, hydronium ion, hydroxide ion, pH, pOH, ICE table, negative logarithm, buffer solution, Henderson-Hasselbalch equation, 0.1000 M, 4.9, 8.9, 2.9.

3 0
3 years ago
Read 2 more answers
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