Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation

And

a=
b=
Now calculate V1 and V2 at given condition

Substitute given values
= 1 x 10^5 , T = 373.15 and given values of coefficients we get

Solve for V1 by iterative or alternative cubic equation solver we get

Similarly solve for state 2 at P2 = 50 bar we get

Now

a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is

a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
attached below is the detailed solution and answers
Explanation:
Attached below is the detailed solution
C(iii) : versus the parameter C
The parameter C is centered in a nonlinear equation, therefore the standard locus will not apply hence when you use a polynomial solver the roots gotten would be plotted against C
Answer:
The given blanks can be filled as given below
Voltmeter must be connected in parallel
Explanation:
A voltmeter is connected in parallel to measure the voltage drop across a resistor this is because in parallel connection, current is divided in each parallel branch and voltage remains same in parallel connections.
Therefore, in order to measure the same voltage across the voltmeter as that of the voltage drop across resistor, voltmeter must be connected in parallel.
Answer:
In refrigeration cycle heat transfer from inside refrigeration
In heat pump cycle heat transfer from environment
Explanation:
heat cycle is mechanical process use for cool the temperature but
In refrigeration heat transfer from inside of refrigeration that decrease temperature of refrigerator and in heat pump it decrease temperature negligible as compare to refrigerator