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exis [7]
4 years ago
15

A chemical reaction between iron atoms and oxygen molecules can only occur if

Chemistry
2 answers:
Umnica [9.8K]4 years ago
8 0
The answer is D because in order for a reaction to take place there must be collisions between the iron and oxygen atoms
algol [13]4 years ago
7 0
<span>Answer: option (4) there are effective collisions between the particles
</span>
<span /><span /><span>
Justification:
</span><span />

<span>The collision theory explains the chemical reactions in terms of collisions. A chemical reaction takes place if two molecules collide effectively.
</span><span />

<span>So, the first conditon is that the collision occur.
</span><span />

<span>The second condition, that the collision be effective requires two conditions:
</span><span>
</span><span>
</span><span>1) that the collision occurs with the proper orientation of the molecules, and
</span><span>
</span><span>
</span><span>2) that the energy of collision be high enough to start the break of the original bonds ant the creation of the new bonds in the activated complex.</span><span /><span />

<span>The energy required to form this activated complex is the activation energy.
</span><span />

<span>So, an effective collision requires the proper orientation of the molecules when they collide and that the energy be equal or greater than the activation energy.
</span>

Temperature and catalyst are factors that affect the occurrence of those collisions, so they affect the rate of the reaction, by modifiying the number of collisions.
<span />
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Draw the alkene formed when 1-heptyne is treated with hbr in the presence of peroxide.
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<h2>Heptene formed is -</h2><h2>CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr</h2>

Explanation:

The two possibilities when the peroxide is not present

  • CH_{3}-CH_{2}-CH_{2}-CH_{2}-CH_{2}-C≡CH +HBr → CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_{2}

  • CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_2 + HBr →CH_3-CH_2-CH_2-CH_2-CH_2-CBr_2-CH_3

In presence peroxide,

CH_3-CH_2-CH_2-CH_2-CH_2-C≡CH+ HBr →CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr

  • When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
  • This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
  • One mole of HBr adds to one mole of 1-heptane.
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