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Answer:
(c) The retention time would be higher (d) The retention time would be lower.
Explanation:
For the polar solutes which were separated using the hydrophilic interaction chromatography (HILIC) with a strongly polar bonded phase, the retention time would be higher if eluent were changed from 80 vol% to 90 vol% acetonitrile in water.
However, for the polar solutes which were separated using the normal-phase chromatography on bare silica with methyl t=butyl ether and 2-propanol solvent, the retention time would be lower if the eluent were changed from 40 vol% to 60 vol% 2-propanol.
The balanced reaction
is:
4NH3 + 3O2 --> 2N2 + 6H2O
<span>We
are given the amount of reactants to be used for the reaction. This
will be the starting point of our calculation.</span>
83.7g of O2 ( 1 mol / 32 g) = 2.62 mol O2
2.81 moles of NH3
From the balanced reaction, we have a 4:3 ratio of the reactants. The limiting reactant would be oxygen. We will use the amount for oxygen for further calculations.
<span>2.62 mol O2</span><span> (6 mol H2O / 3 mol O2) (18.02 g H2O / 1 mol H2O) = 94.42 g H2O</span>