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Varvara68 [4.7K]
3 years ago
15

Which of the subshells below do not exist due to the constraints upon the angular momentum quantum number?A) 2dB) 2sC) 2pD) all

of the aboveE) none of the above
Chemistry
1 answer:
Gnom [1K]3 years ago
7 0

Answer:

  • Option A): <em>Due to the constraints upton the angular momentum quantum number, the subshell </em><u><em>2d</em></u><em> does not exist.</em>

Explanation:

The <em>angular momentum quantum number</em>, identified with the letter l (lowercase L),  number is the second quantum number.

This number identifies the shape of the orbital or <em>kind of subshell</em>.

The possible values of the angular momentum quantum number, l, are constrained by the value of the principal quantum number n: l can take values from 0 to n - 1.

So, you can use this guide:

Principal quantum   Angular momentum         Shape of the orbital

number, n                 quantum number, l

         1                                      0                             s

         2                                     0, 1                          s, p

         3                                     0, 1, 2                      s, p, d

Hence,

  • <u>the subshell 2d (n = 2, l = 2) is not feasible</u>.

  • 2s (option B) is possible: n = 2, l = 0

  • 2p (option C) is possible: n = 2, l = 1

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When you combine 50.0 mL of 0.100 M AgNO3 with 50.0 mL of 0.100 M HCl in a coffee-cup calorimeter, the temperature changes from
RideAnS [48]

Answer : The enthalpy of reaction (\Delta H_{rxn}) is, 67.716 KJ/mole

Explanation :

First we have to calculate the moles of AgNO_3 and HCl.

\text{Moles of }AgNO_3=\text{Molarity of }AgNO_3\times \text{Volume}=(0.100mole/L)\times (0.05L)=0.005mole

\text{Moles of }HCl=\text{Molarity of }HCl\times \text{Volume}=(0.100mole/L)\times (0.05L)=0.005mole

Now we have to calculate the moles of AgCl formed.

The balanced chemical reaction will be,

AgNO_3(aq)+HCl(aq)\rightarrow AgCl(s)+HNO_3(aq)

As, 1 mole of AgNO_3 react with 1 mole of HCl to give 1 mole of AgCl

So, 0.005 mole of AgNO_3 react with 0.005 mole of HCl to give 1 mole of AgCl

The moles of AgCl formed  = 0.005 mole

Total volume of the solution = 50.0 ml + 50.0 ml = 100.0 ml

Now we have to calculate the mass of solution.

Mass of the solution = Density of the solution × Volume of the solution

Mass of the solution = 1.00 g/ml × 100.0 ml = 100 g

Now we have to calculate the heat.

q=m\times C\Delta T=m\times C \times (T_2-T_1)

where,

q = heat

C = specific heat capacity = 4.18J/g^oC

m = mass = 100 g

T_2 = final temperature = 24.21^oC

T_1 = initial temperature = 23.40^oC

Now put all the given values in the above expression, we get:

q=100g\times (4.18J/g^oC)\times (24.21-23.40)^oC

q=338.58J

Now  we have to calculate the enthalpy of the reaction.

\Delta H_{rxn}=\frac{q}{n}

where,

\Delta H_{rxn} = enthalpy of reaction = ?

q = heat of reaction = 338.58 J

n = moles of reaction = 0.005 mole

Now put all the given values in above expression, we get:

\Delta H_{rxn}=\frac{338.58J}{0.005mole}=6771.6J/mole=67.716KJ/mole

Conversion used : (1 KJ = 1000 J)

Therefore, the enthalpy of reaction (\Delta H_{rxn}) is, 67.716 KJ/mole

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