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2 years ago

Calculate the pressure in atmospheres of 0.5 mol of Helium ( He) at 20°C & occupying 2.50 L.

Chemistry

1 answer:

Morgarella [4.7K]2 years ago

7 0

Answer:

4.811 atm.

Explanation:

We can use the general law of ideal gas: PV = nRT.

where, P is the pressure of the gas in atm (P = ?? atm).

V is the volume of the gas in L (V = 2.5 L).

n is the no. of moles of the gas in mol (n = 0.5 mol).

R is the general gas constant (R = 0.0821 L.atm/mol.K),

T is the temperature of the gas in K (T = 20°C + 273 = 293 K).

∴ P = nRT/V = (0.5 mol)(0.0821 L.atm/mol.K)(293 K)/(2.5 L) = 4.811 atm.

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2 years ago

The heat of fusion AH, of ethyl acetate (C4H802) is 10.5 kinol. Calculate the change in entropy as when 398. g of ethy, acetate

Hitman42 [59]

Answer: The entropy change of the ethyl acetate is 133. J/K

Explanation:

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$

Given mass of ethyl acetate = 398 g

Molar mass of ethyl acetate = 88.11 g/mol

Putting values in above equation, we get:

$\text{Moles of ethyl acetate}=\frac{398g}{88.11g/mol}=4.52mol$

To calculate the entropy change for different phase at same temperature, we use the equation:

$\Delta S=n\times \frac{\Delta H_{fusion}}{T}$

where,

$\Delta S$ = Entropy change = ?

n = moles of ethyl acetate = 4.52 moles

$\Delta H_{fusion}$ = enthalpy of fusion = 10.5 kJ/mol = 10500 J/mol (Conversion factor: 1 kJ = 1000 J)

T = temperature of the system = $84.0^oC=[84+273]K=357K$

Putting values in above equation, we get:

$\Delta S=\frac{4.52mol\times 10500J/mol}{357K}\\\\\Delta S=132.9J/K$

Hence, the entropy change of the ethyl acetate is 133. J/K

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