Because they are more in close proximity to the core atom's nucleus than lone pairs are, lone pairs reject other lone pairs more strongly than bonding pairs do effect the bond angle.
When a single pair of electrons at the central atom begins to resist the bound pair of electrons, the bond angle decreases and the bonds are slightly shifted inward. It moves existing atoms closer together and modifies their geometry. It's equivalent to include an atom. When there is an increase in back bonding, the bond angle rises. Because the lone pair electrons of the two atoms reject one another, adjacent atoms in a molecule that have lone pair electrons will not be kept together in their bond as securely.
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Answer:
Moles of carbon dioxide gas is 0.584 moles.
Mass of 0.584 moles of carbon dioxide gas is 25.7 g
Explanation:
Using ideal gas equation
PV = nRT
where,
P = Pressure of gas = 
V = Volume of gas = 30.0 L
n = number of moles of gas = ?
R = Gas constant = 0.0821 L.atm/mol.K
T = Temperature of gas = 27°C = 300.15 K
Putting values in above equation, we get:
Moles of carbon dioxide gas = 0.584 moles
Mass of 0.584 moles of carbon dioxide gas = 0.584 mol × 44 g/mol = 25.69 g ≈ 25.7 g
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Explanat hope it helps
