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UNO [17]
3 years ago
10

A 0.0447−mol sample of a nutrient substance, with a formula weight of 114 g/mol, is burned in a bomb calorimeter containing 6.19

× 102 g H2O. Given that the fuel value is 6.13 × 10−1 in nutritional Cal when the temperature of the water is increased by 5.05°C, what is the fuel value in kJ in scientific notation?
Chemistry
1 answer:
worty [1.4K]3 years ago
4 0

Answer:

The value is  x = 2.565 *10^{3} \  kJ/kg

Explanation:

From the question we are told that

  The  no of moles of the sample is  n = 0.0447 mole

  The formula weight is  M  =  114 \ g/mol

   The  mass of water is  m = 6.19 *10^{2}\  g

   The amount of the fuel is  f= 6.13*10^{-1} \  nutritional \ Cal

   The temperature rise is  \Delta  T  =  5.05^o

Generally

      1 \  nutritional \ Cal => 4.184*10^{3}  \ kJ/kg

=>  f= 6.13*10^{-1} \  nutritional \ Cal \to x

=>     x =  \frac{6.13 *10^{-1} * 4.184 *10^{3}}{1}

=>     x = 2.565 *10^{3} \  kJ/kg

   

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Give the direction of the reaction, if K >> 1. Give the direction of the reaction, if K >> 1. The forward reaction i
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Answer:

A. for K>>1 you can say that the reaction is nearly irreversible so the forward direction is favored. (Products formation)

B. When the temperature rises the equilibrium is going to change but to know how is going to change you have to take into account the kind of reaction. For endothermic reactions (the reverse reaction is favored) and for exothermic reactions (the forward reaction is favored)

Explanation:

A. The equilibrium constant K is defined as

K=\frac{Products}{reagents}

In any case  

aA +Bb  equilibrium Cd +dD

where K is:

K= \frac{[C]^{c}[D]^{d}}{[A]^{a}[B]^{b}}

[] is molar concentration.

If K>>> 1 it means that the molar concentration of products is a lot bigger that the molar concentration of reagents, so the forward reaction is favored.

B. The relation between K and temperature is given by the Van't Hoff equation

ln(\frac{K_{1}}{K_{2}})=\frac{-delta H^{o}}{R}*(\frac{1}{T_{1}}-\frac{1}{T_{2}})

Where: H is reaction enthalpy, R is the gas constant and T temperature.  

Clearing the equation for K_{2} we get:

K_{2}=\frac{K_{1}}{e^{\frac{-deltaH^{o}}{R}*(\frac{1}{T_{1}} -\frac{1}{T_{2}})}}

Here we can study two cases: when delta H^{o} is positive (exothermic reactions) and when is negative (endothermic reactions)

For exothermic reactions when we increase the temperature the denominator in the equation would have a negative exponent so K_{2} is greater that K_{1} and the forward reaction is favored.

When we have an endothermic reaction we will have a positive exponent so K_{2} will be less than K_{1} the forward reactions is not favored.  

{e^{\frac{-deltaH^{o}}{R}*(\frac{1}{T_{1}} -\frac{1}{T_{2}})}}

5 0
3 years ago
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