Answer:
a) Pabs = 48960 KPa
b) T = 433.332 °C
Explanation:
∴ d = 1000 Kg/m³
∴ g = 9.8 m/s²
∴ h = 5000 m
∴ P gauge = - 40 KPa * ( 1000 Pa / KPa ) = - 40000 Pa; Pa≡Kg/m*s²
⇒ Pabs = - 40000 Kg/ms² + ( 1000 Kg/m³ * 9.8 m/s² * 5000 m )
⇒ Pabs = 48960000 Pa = 48960 KPa
a) at that height and pressure, we find the temperature at which the water boils by means of an almost-exponential graph which has the following equation:
P(T) = 0.61094 exp ( 17.625*T / ( T + 243.04 ))......P (KPa) ∧ T (°C)....from literature
∴ P = 48960 KPa
⇒ ( 48960 KPa / 0.61094 ) = exp ( 17.625T / (T+ 243.04))
⇒ 80138.803 = exp ( 17.625T / ( T + 243.04))
⇒ Ln ( 80138.803) = 17.625T / ( T + 243.04))
⇒ 11.292 * ( T + 243.04 ) = 17.625T
⇒ 11.292T + 2744.289 = 17.625T
⇒ 2744.289 = 17.625T - 11.292T
⇒ 2744.289 = 6.333T
⇒ T = 433.332 °C
Answer:
The new pressure is 53.3 kPa
Explanation:
This problem can be solved by this law. when the volume remains constant, pressure changes directly proportional as the Aboslute T° is modified.
T° increase → Pressure increase
T° decrease → Pressure decrease
In this case, temperature was really decreased. So the pressure must be lower.
P₁ / T₁ = P₂ / T₂
80 kPa / 300K = P₂/200K
(80 kPa / 300K) . 200 K = P₂ → 53.3 kPa
Fe^2 O^3 + 6HCl --> 2FeCl^3 + 3H^2 O
Answer : The rate constant at 785.0 K is, 
Explanation :
According to the Arrhenius equation,

or,
![\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7BK_1%7D%29%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= rate constant at
= 
= rate constant at
= ?
= activation energy for the reaction = 262 kJ/mole = 262000 J/mole
R = gas constant = 8.314 J/mole.K
= initial temperature = 
= final temperature = 
Now put all the given values in this formula, we get:
![\log (\frac{K_2}{6.1\times 10^{-8}s^{-1}})=\frac{262000J/mole}{2.303\times 8.314J/mole.K}[\frac{1}{600.0K}-\frac{1}{785.0K}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7B6.1%5Ctimes%2010%5E%7B-8%7Ds%5E%7B-1%7D%7D%29%3D%5Cfrac%7B262000J%2Fmole%7D%7B2.303%5Ctimes%208.314J%2Fmole.K%7D%5B%5Cfrac%7B1%7D%7B600.0K%7D-%5Cfrac%7B1%7D%7B785.0K%7D%5D)

Therefore, the rate constant at 785.0 K is, 
Adding perchloric acid to water would cause it's conductivity to increase.