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3 years ago

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Chemistry

1 answer:

larisa [96]3 years ago

3 0

Answer:

In FeO iron atom exist as Fe+ cation but in Fe2O3 iron atom exist as Fe3+ cation.

Explanation:

Feo=Fe+ + O-

Fe2O3 =2Fe3+ + 3O2-

The difference in the charge of iron cation deeply affect the compound formulas because in FeO the Fe cation has 1 unit positive charge where in Fe2O3 the Fe cation has 3 units positive charge.

That"s why these two chemical compounds made up of similar atoms differ in their chemical formulas.

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Challenge question: This question is worth 6 points. As you saw in problem 9 we can have species bound to a central metal ion. T

GenaCL600 [577]

Answer:

CN^- is a strong field ligand

Explanation:

The complex, hexacyanoferrate II is an Fe^2+ specie. Fe^2+ is a d^6 specie. It may exist as high spin (paramagnetic) or low spin (diamagnetic) depending on the ligand. The energy of the d-orbitals become nondegenerate upon approach of a ligand. The extent of separation of the two orbitals and the energy between them is defined as the magnitude of crystal field splitting (∆o).

Ligands that cause a large crystal field splitting such as CN^- are called strong field ligands. They lead to the formation of diamagnetic species. Strong field ligands occur towards the end of the spectrochemical series of ligands.

Hence the complex, Fe(CN)6 4− is diamagnetic because the cyanide ion is a strong field ligand that causes the six d-electrons present to pair up in a low spin arrangement.

5 0

3 years ago

Titanium is a transition metal used in many alloys because it is extremely strong and lightweight. Titanium tetrachloride (TiCl4

vova2212 [387]

Answer:

a) 226.6 grams of Cl₂

b) 19.2 grams of C

c) 303.2 grams of TiCl₄ and 70.4 grams of CO₂

Explanation:

The balanced chemical reaction is the following:

TiO₂(s) + C(s) + 2 Cl₂(g) → TiCl₄(s) + CO₂(g)

(a) What mass of Cl₂ gas is needed to react with 1.60 mol TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 2 moles of Cl₂. So, the stoichiometric ratio is 2 mol Cl₂/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of Cl₂ we need:

1.60 mol TiO₂ x 2 mol Cl₂/1 mol TiO₂ = 3.2 mol Cl₂

Now, we convert from moles to mass by using the molecular weight (MW) of Cl₂:

MW(Cl₂) = 35.4 g/mol x 2 = 70.8 g/mol

mass of Cl₂= 3.2 mol x 70.8 g/mol = 226.6 g

Therefore, 226.6 grams of Cl₂ are needed to react with 1.6 mol of TiO₂.

(b) What mass of C is needed to react with 1.60 mol of TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 1 moles of C(s). So, the stoichiometric ratio is 1 mol C/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of C(s) we need:

1.60 mol TiO₂ x 1 mol C(s)/1 mol TiO₂ = 1.60 mol C(s)

So, we convert the moles of C(s) to grams as follows:

MW(C) = 12 g/mol

1.60 mol x 12 g/mol = 19.2 g C(s)

Therefore, a mass of 19.2 grams of C is needed to react with 1.60 mol of TiO₂.

(c) What is the mass of all the products formed by reaction with 1.60 mol of TiO₂?

From the chemical equation, we can notice that 1 mol of TiO₂ produces 1 mol of TiCl₄ and 1 mol of CO₂. So, from 1.60 moles of TiO₂, 1 mol of each product will be produced:

1 mol TiO₂/1 mol TiCl₄ ⇒ 1.60 mol TiO₂/1.60 mol TiCl₄

1 mol TiO₂/1 mol CO₂ ⇒ 1.60 mol TiO₂/1.60 mol CO₂

Finally, we convert the moles to grams by using the molecular weight of each compound:

MW(TiCl₄) = 47.9 g/mol Ti + (35.4 g/mol x 4 Cl) = 189.5 g/mol

1.60 mol x 189.5 g/mol = 303.2 g

MW(CO₂) = 12 g/mol C + (16 g/mol x 2 O) = 44 g/mol

1.60 mol x 44 g/mol = 70.4 g

Therefore, from the reaction of 1.60 mol of TiO₂ are formed 303.2 grams of TiCl₄ and 70.4 grams of CO₂.

3 0

3 years ago

100!!!POINTS PLZ HELP Explain (on the molecular level) what pumping a tire with air will do to

Bas_tet [7]

Answer:

Gases are easily compressed. We can see evidence of this in Table 1 in Thermal Expansion of Solids and Liquids, where you will note that gases have the largest coefficients of volume expansion. The large coefficients mean that gases expand and contract very rapidly with temperature changes. In addition, you will note that most gases expand at the same rate, or have the same β. This raises the question as to why gases should all act in nearly the same way, when liquids and solids have widely varying expansion rates.

The answer lies in the large separation of atoms and molecules in gases, compared to their sizes, as illustrated in Figure 2. Because atoms and molecules have large separations, forces between them can be ignored, except when they collide with each other during collisions. The motion of atoms and molecules (at temperatures well above the boiling temperature) is fast, such that the gas occupies all of the accessible volume and the expansion of gases is rapid. In contrast, in liquids and solids, atoms and molecules are closer together and are quite sensitive to the forces between them.

3 0

4 years ago

C. Neither a Physical or Chemical Changu

Nutka1998 [239]

Explanation:

I think B a chemical change

5 0

3 years ago

Entropy can be thought of as the degree of disorganization of a system. TRUE FALSE

Mice21 [21]

Answer:

True

Explanation:

The entropy of a system denoted by S is a thermodynamic function that increases in value when there are more ways to arrange the particles in the system. Some spontaneous chemical processes are entropy driven. An increase in entropy is said to drive the dissolution of ionic salts along with the evaporation of water are related to the spreading out of energy.

The entropy of a system can be taken as a measure of disorder of a system. In a spontaneous chemical process, the entropy of the universe is said to increase. ΔSunivu>0. Making the answer true.

7 0

3 years ago