Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation

And

a=
b=
Now calculate V1 and V2 at given condition

Substitute given values
= 1 x 10^5 , T = 373.15 and given values of coefficients we get

Solve for V1 by iterative or alternative cubic equation solver we get

Similarly solve for state 2 at P2 = 50 bar we get

Now

a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is

a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer: the half-angle "alpha" of the Mach cone = 30⁰
Explanation:
To calculate the half-angle "alpha" of the Mach cone.
we say ;
Sin∝ = 1 / Ma
given that Ma = 2
now we substitute
Sin∝ = 1 / 2
Sin∝ = 0.5
∝ = Sin⁻¹ 0.5
∝ = 30⁰
Therefore, the half-angle "alpha" of the Mach cone is 30⁰
Answer:
The electric current from the batteries installed in a radio supplies direct current (DC) electricity to the radio components directly as an alternative source to the Alternating Current (AC) converted to DC by the power unit located at the radio end of the cable plugged into the wall outlet.
Explanation:
Part of the power unit in a radio includes an AC to DC converter, which is an electrical circuit that is able to convert the alternating current power input from the wall outlet into a direct current output to the radio with which the radio can work
The alternative source of electric current from the batteries installed in a radio bypasses the AC to DC converter and supplies power directly to the radio so it can also work.
Answer:
Departure rate = 7.65 vehicle/min
Explanation:
See the attached file for the calculation.