Answer : The work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Explanation :
(a) At constant volume condition the entropy change of the gas is:

We know that,
The relation between the
for an ideal gas are :

As we are given :



Now we have to calculate the entropy change of the gas.


(b) As we know that, the work done for isochoric (constant volume) is equal to zero. 
(C) Heat during the process will be,

Therefore, the work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Hydrogen mass is 1, the atom with mass number 7 is Lithium
Answer : Electron P has greater energy difference than the Electron N.
Explanation :
Wavelength range of violet light = 400 - 500 nm
Wavelength range of orange light = 600 - 700 nm
The Planck's equation is,

where,
E = energy of light
c = speed of light
= wavelength of light
According to the Planck's equation, wavelength and energy follow inverse relation. As the wavelength increases, energy decreases.
From the given spectrum, the wavelength of violet light is less. We conclude that When electron P gives violet light on transition it means that energy difference between the energy level was high.
From the given spectrum, the wavelength of orange light is more. We conclude that When electron N gives orange light on transition it means that energy difference between the energy level was low.
So, Electron P which gives violet light on transition has greater energy difference than the Electron N.
The answer is 163.333993748 grams