The heat content of a system.
Answer:
FALSE
Explanation:
Br is <em>bromine</em> with atomic number 35, mass number of 79.904 and belongs to the group 7 elements known as the halogens.
Ga is <em>gallium</em> with atomic number 31, mass number of 69.72 and belongs to the alkaline earth metal i.e the group 3 elements.
From the above and in terms of their mass number, it is evident that Br is the larger element compared to Ga which is lesser than Br. Hence the statement is FALSE
water vapor>liquid water> ice is the correct order of increasing standard molar entropy.
Since water has more entropy than ice, melting is encouraged by entropy. However, ice has less energy than water, which means that energy favors freezing. The distinction between liquid water, ice, and water vapor is that each of them is a different state of matter. Ice represents the solid state, liquid water the liquid state, and water vapor the gaseous state of water. As a result, the system's entropy reduces. A vapour condensing is an exothermic process. Consequently, the environment's entropy rises. however, the environment's growth in entropy grows. Since the gas state has a higher entropy than the liquid state does, the entropy change for the vaporization of water is positive.
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Answer : The correct option is, (a) paramagnetic with two unpaired electrons.
Explanation :
According to the molecular orbital theory, the general molecular orbital configuration will be,
![(\sigma_{1s}),(\sigma_{1s}^*),(\sigma_{2s}),(\sigma_{2s}^*),(\sigma_{2p_z}),[(\pi_{2p_x})=(\pi_{2p_y})],[(\pi_{2p_x}^*)=(\pi_{2p_y}^*)],(\sigma_{2p_z}^*)](https://tex.z-dn.net/?f=%28%5Csigma_%7B1s%7D%29%2C%28%5Csigma_%7B1s%7D%5E%2A%29%2C%28%5Csigma_%7B2s%7D%29%2C%28%5Csigma_%7B2s%7D%5E%2A%29%2C%28%5Csigma_%7B2p_z%7D%29%2C%5B%28%5Cpi_%7B2p_x%7D%29%3D%28%5Cpi_%7B2p_y%7D%29%5D%2C%5B%28%5Cpi_%7B2p_x%7D%5E%2A%29%3D%28%5Cpi_%7B2p_y%7D%5E%2A%29%5D%2C%28%5Csigma_%7B2p_z%7D%5E%2A%29)
As there are 14 electrons present in the given configuration.
The molecular orbital configuration of molecule will be,
![(\sigma_{1s})^2,(\sigma_{1s}^*)^2,(\sigma_{2s})^2,(\sigma_{2s}^*)^2,(\sigma_{2p_z})^2,[(\pi_{2p_x})^1=(\pi_{2p_y})^1],[(\pi_{2p_x}^*)^0=(\pi_{2p_y}^*)^0],(\sigma_{2p_z}^*)^0](https://tex.z-dn.net/?f=%28%5Csigma_%7B1s%7D%29%5E2%2C%28%5Csigma_%7B1s%7D%5E%2A%29%5E2%2C%28%5Csigma_%7B2s%7D%29%5E2%2C%28%5Csigma_%7B2s%7D%5E%2A%29%5E2%2C%28%5Csigma_%7B2p_z%7D%29%5E2%2C%5B%28%5Cpi_%7B2p_x%7D%29%5E1%3D%28%5Cpi_%7B2p_y%7D%29%5E1%5D%2C%5B%28%5Cpi_%7B2p_x%7D%5E%2A%29%5E0%3D%28%5Cpi_%7B2p_y%7D%5E%2A%29%5E0%5D%2C%28%5Csigma_%7B2p_z%7D%5E%2A%29%5E0)
The number of unpaired electron in the given configuration is, 2. So, this is paramagnetic. That means, more the number of unpaired electrons, more paramagnetic.
Hence, the correct option is, (a) paramagnetic with two unpaired electrons.
