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marshall27 [118]
2 years ago
6

1.Write out the net equation for the dissolution of the ionic compound KNO3.

Chemistry
1 answer:
frosja888 [35]2 years ago
4 0

Answer:

1. KNO3(s) ------> K^+(aq) + NO3^-(aq)

2. The dissolution is endothermic

3. The sign of the enthalpy of dissolution is positive

Explanation:

The sign of the enthalpy of dissolution depends on the hydration energy and the lattice energy.

For KNO3, the hydration energy is less than the lattice energy hence the dissolution is endothermic and the enthalpy of dissolution is positive.

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Agree or disagree? Explain (2 ideas, 2 examples)
yawa3891 [41]

Answer:

Agree this is correct if it not blame me

6 0
3 years ago
Calculate the pH of the following simple solutions:
IceJOKER [234]

Answer :

(1) pH = 1.27

(2) pH = 13.35

(3) The given solution is not a buffer.

Explanation :

<u>(1) 53.1 mM HCl</u>

Concentration of HCl = 53.1mM=53.1\times 10^{-3}M

As HCl is a strong acid. So, it dissociates completely to give hydrogen ion and chloride ion.

So, Concentration of hydrogen ion= 53.1\times 10^{-3}M

pH : It is defined as the negative logarithm of hydrogen ion concentration.

pH=-\log [H^+]

pH=-\log (53.1\times 10^{-3})

pH=1.27

<u>(2) 0.223 M KOH</u>

Concentration of KOH = 0.223 M

As KOH is a strong base. So, it dissociates completely to give hydroxide ion and potassium ion.

So, Concentration of hydroxide ion= 0.223 M

Now we have to calculate the pOH.

pOH=-\log [OH^-]

pOH=-\log (0.223)

pOH=0.65

Now we have to calculate the pH.

pH+pOH=14\\\\pH=14-pOH\\\\pH=14-0.65=13.35

<u>(3) 53.1 mM HCl + 0.223 M KOH</u>

Buffer : It is defined as a solution that maintain the pH of the solution by adding the small amount of acid or a base.

It is not a buffer because HCl is a strong acid and KOH is a strong base. Both dissociates completely.

As we know that the pH of strong acid and strong base solution is always 7.

So, the given solution is not a buffer.

5 0
3 years ago
Use the given data at 500 K to calculate ΔG°for the reaction
Anton [14]

Answer : The  value of \Delta G^o for the reaction is -959.1 kJ

Explanation :

The given balanced chemical reaction is,

2H_2S(g)+3O_2(g)\rightarrow 2H_2O(g)+2SO_2(g)

First we have to calculate the enthalpy of reaction (\Delta H^o).

\Delta H^o=H_f_{product}-H_f_{reactant}

\Delta H^o=[n_{H_2O}\times \Delta H_f^0_{(H_2O)}+n_{SO_2}\times \Delta H_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta H_f^0_{(H_2S)}+n_{O_2}\times \Delta H_f^0_{(O_2)}]

where,

\Delta H^o = enthalpy of reaction = ?

n = number of moles

\Delta H_f^0 = standard enthalpy of formation

Now put all the given values in this expression, we get:

\Delta H^o=[2mole\times (-242kJ/mol)+2mole\times (-296.8kJ/mol)}]-[2mole\times (-21kJ/mol)+3mole\times (0kJ/mol)]

\Delta H^o=-1035.6kJ=-1035600J

conversion used : (1 kJ = 1000 J)

Now we have to calculate the entropy of reaction (\Delta S^o).

\Delta S^o=S_f_{product}-S_f_{reactant}

\Delta S^o=[n_{H_2O}\times \Delta S_f^0_{(H_2O)}+n_{SO_2}\times \Delta S_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta S_f^0_{(H_2S)}+n_{O_2}\times \Delta S_f^0_{(O_2)}]

where,

\Delta S^o = entropy of reaction = ?

n = number of moles

\Delta S_f^0 = standard entropy of formation

Now put all the given values in this expression, we get:

\Delta S^o=[2mole\times (189J/K.mol)+2mole\times (248J/K.mol)}]-[2mole\times (206J/K.mol)+3mole\times (205J/K.mol)]

\Delta S^o=-153J/K

Now we have to calculate the Gibbs free energy of reaction (\Delta G^o).

As we know that,

\Delta G^o=\Delta H^o-T\Delta S^o

At room temperature, the temperature is 500 K.

\Delta G^o=(-1035600J)-(500K\times -153J/K)

\Delta G^o=-959100J=-959.1kJ

Therefore, the value of \Delta G^o for the reaction is -959.1 kJ

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