6. a) Why is isocyanic acid prepared ""in situ"" in the Dulcin experiment? [2 pts] b) Draw a plausible Lewis structure for isocy
anic acid showing all lone pairs. The connectivity for isocyanic acid is shown below[4 pts] H-N-C-0
1 answer:
Answer:
As it gets hydrolyzed easily.
Explanation:
The isocyanic acid may get polymerizes easily into cyanuric acid and a polymer cyamelide
Also, even at 0 °C temperature it may react with mositure and gets hydrolyzed into ammonia an carbon dioxide. Thus we generally prepare it in situ. Even after synthesis it is stroed at dry ice or liquid nitrogen at very low temperature.
The lewis structure is shown in the figure.
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Answer:
2,2,3,3-tetrapropyloxirane
Explanation:
In this case, we have to know first the alkene that will react with the peroxyacid. So:
<u>What do we know about the unknown alkene? </u>
We know the product of the ozonolysis reaction (see figure 1). This reaction is an <u>oxidative rupture reaction</u>. Therefore, the double bond will be broken and we have to replace the carbons on each side of the double bond by oxygens. If is the only product we will have a symmetric molecule in this case 4,5-dipropyloct-4-ene.
<u>What is the product with the peroxyacid?</u>
This compound in the presence of alkenes will produce <u>peroxides.</u> Therefore we have to put a peroxide group in the carbons where the double bond was placed. So, we will have as product <u>2,2,3,3-tetrapropyloxirane.</u> (see figure 2)
1. 1086.04 mmHg
2.70.213 mmHg
3. 95.954 kPa
<h3>Further explanation</h3>Pressure (P) is the force applied per unit area
Can be formulated :
P = pressure (SI=Pascal(Pa))
F= force applied (N)
A=area(m²)
The unit of pressure can be expressed in atm, mmHg, or Pascal