Question

Use the molar bond enthalpy data in the table to estimate the value of Δ∘rxn

Answer 1

Answer:

-420

Explanation:

Answer 2

Answer:

ΔH°rxn = - 433.1 KJ/mol

Explanation:

• CH4(g) + 4Cl2(g) → CCl4(g) + 4HCl(g)

⇒ ΔH°rxn = 4ΔH°HCl(g) + ΔH°CCl4(g) - 4ΔH°Cl2(g) - ΔH°CH4(g)

∴ ΔH°Cl2(g) = 0 KJ/mol.....pure element in its reference state

∴ ΔH°CCl4(g) = - 138.7 KJ/mol

∴ ΔH°HCl(g) = - 92.3 KJ/mol

∴ ΔH°CH4(g) = - 74.8 KJ/mol

⇒ ΔH°rxn = 4(- 92.3 KJ/mol) + (- 138.7 KJ/mol) - 4(0 KJ/mol) - (- 74.8 KJ/mol)

⇒  ΔH°rxn = - 369.2 KJ/mol - 138.7 KJ/mol - 0 KJ/mol + 74.8 KJ/mol

⇒ ΔH°rxn = - 433.1 KJ/mol