<u>Answer:</u> The correct answer is 
<u>Explanation:</u>
Synthesis reaction is defined as the reaction in which two smaller substances combine together to form a large single compound.

For the given options:
<u>Option 1:</u> 
These two combination produces hydrochloric acid and bromine gas. The reaction is known as single displacement reaction.

<u>Option 2:</u> 
These two combination produces calcium hydroxide and hydrogen gas. The reaction is known as single displacement reaction.

<u>Option 3:</u> 
These two combination produces magnesium hydroxide only. The reaction is known as synthesis reaction.

<u>Option 4:</u> 
These two combination produces carbon dioxide and water molecule. The reaction is known as combustion reaction.

From the above information, the correct answer is 