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dolphi86 [110]
4 years ago
12

Consider the following reaction.Cr2O3(s) + 3CCl4(l) 2CrCl3(s) + 3COCl2(g). When the green solid is mixed with the colorless liq

uid, the mixture starts to bubble and fume. When all action has stopped, a dry purple solid containing solid green specks remains. Which substance is the limiting reactant?A) Cr2O3B) CCl4C) CrCl3D) COCl2E) there is no limiting reactant
Chemistry
1 answer:
Elena L [17]4 years ago
6 0

Answer:

The answer to your question is: letter B

Explanation:

Reaction

                 Cr2O3(s)   +   3CCl4(l)   ⇒  2CrCl3(s)  +   3COCl2(g)

From the information given and the reaction, we can conclude that:

Green solid = Cr2O3 (s)     "s" means solid

Colorless liquid = CCl4 (l)    "l" means liquid   and is the other reactant

Purple solid = CrCl3(s)        CrCl3 is purple and "s" solid

Then, as a green specks remains it means that the excess reactant is Cr2O3, so, CCl4 is the limiting reactant.

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An ideal gas in a sealed container has an initial volume of 2.80 L. At constant pressure, it is cooled to 18.00 °C, where its
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In this case, given the T-V variation, we understand it is possible to apply the Charles' law as shown below:

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T_1= \frac{T_2V_1}{V_2}\\\\T_1= \frac{(18.00+273.15)K(1.75L)}{(2.80L)}\\\\T_1=182K-273.15\\\\T_1=-91.18\°C

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Consider the following reaction: CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at25 ∘C under these conditions: PCO2PCC
Salsk061 [2.6K]

<u>Answer:</u> The \Delta G for the reaction is 54.6 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)

We are given:

\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol

  • To calculate \Delta G^o_{rxn} for the reaction, we use the equation:

\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]

For the given equation:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]

Putting values in above equation, we get:

\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J

Conversion factor used = 1 kJ = 1000 J

  • The expression of K_p for the given reaction:

K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}

We are given:

p_{COCl_2}=0.760atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.180atm

Putting values in above equation, we get:

K_p=\frac{(0.760)^2}{0.140\times 0.180}\\\\K_p=22.92

  • To calculate the Gibbs free energy of the reaction, we use the equation:

\Delta G=\Delta G^o+RT\ln K_p

where,

\Delta G = Gibbs' free energy of the reaction = ?

\Delta G^o = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = 8.314J/K mol

T = Temperature = 25^oC=[25+273]K=298K

K_p = equilibrium constant in terms of partial pressure = 22.92

Putting values in above equation, we get:

\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(22.92))\\\\\Delta G=54659.78J/mol=54.6kJ/mol

Hence, the \Delta G for the reaction is 54.6 kJ/mol

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