Answer : The value of 
for the reaction is -959.1 kJ
Explanation :
The given balanced chemical reaction is,
First we have to calculate the enthalpy of reaction 
.
![\Delta H^o=[n_{H_2O}\times \Delta H_f^0_{(H_2O)}+n_{SO_2}\times \Delta H_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta H_f^0_{(H_2S)}+n_{O_2}\times \Delta H_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28O_2%29%7D%5D)
where,
= enthalpy of reaction = ?
n = number of moles
= standard enthalpy of formation
Now put all the given values in this expression, we get:
![\Delta H^o=[2mole\times (-242kJ/mol)+2mole\times (-296.8kJ/mol)}]-[2mole\times (-21kJ/mol)+3mole\times (0kJ/mol)]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5B2mole%5Ctimes%20%28-242kJ%2Fmol%29%2B2mole%5Ctimes%20%28-296.8kJ%2Fmol%29%7D%5D-%5B2mole%5Ctimes%20%28-21kJ%2Fmol%29%2B3mole%5Ctimes%20%280kJ%2Fmol%29%5D)
conversion used : (1 kJ = 1000 J)
Now we have to calculate the entropy of reaction 
.
![\Delta S^o=[n_{H_2O}\times \Delta S_f^0_{(H_2O)}+n_{SO_2}\times \Delta S_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta S_f^0_{(H_2S)}+n_{O_2}\times \Delta S_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28O_2%29%7D%5D)
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of formation
Now put all the given values in this expression, we get:
![\Delta S^o=[2mole\times (189J/K.mol)+2mole\times (248J/K.mol)}]-[2mole\times (206J/K.mol)+3mole\times (205J/K.mol)]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5B2mole%5Ctimes%20%28189J%2FK.mol%29%2B2mole%5Ctimes%20%28248J%2FK.mol%29%7D%5D-%5B2mole%5Ctimes%20%28206J%2FK.mol%29%2B3mole%5Ctimes%20%28205J%2FK.mol%29%5D)
Now we have to calculate the Gibbs free energy of reaction 
.
As we know that,
At room temperature, the temperature is 500 K.
Therefore, the value of for the reaction is -959.1 kJ
Answer:
a) Aqueous LiBr = Hydrogen Gas
b) Aqueous AgBr = solid Ag
c) Molten LiBr = solid Li
c) Molten AgBr = Solid Ag
Explanation:
a) Aqueous LiBr
This sample produces Hydrogen gas, because the H+ (conteined in the water) has a reduction potential higher than the Li+ from the salt. Therefore the hydrogen cation will reduce instead of the lithium one and form the gas.
b) Aqueous AgBr
This sample produces Solid Ag, because the Ag+ has a reduction potential higher than the H+ from the water. Therefore the silver cation will reduce instead of the hydrogen one and form the solid.
c) Molten LiBr
In a molten binary salt like LiBr there is only one cation present in the cathod. In this case the Li+, so it will reduce and form solid Li.
c) Molten AgBr
The same as the item above: there is only one cation present in the cathod. In this case the Ag+, so it will reduce and form solid Ag.
Evaporation technique is used to separate a compound dissolved in a solvent by vaporizing the solvent and converting it to gaseous state. This leaves behind the solid residue present in the solution after the pure solvent is vaporized. The solvent vapors can be collected and condensed to get pure solvent. But the solid residue cannot be considered pure as it is the left over solid after all the solvent is evaporated. If the solution has some impurities, the solid left over includes all of the impurities. So, we cannot obtain a pure solid in evaporation technique.
The problem can solved using the heat equation which is expressed as:
H = mCΔT
where H is the energy absorbed or released, m is the mass of the substance, C is the specific heat capacity, and ΔT is the change in temperature.
2208 J = 41 g x 4.18 J/g·°C x ( T - 24 °C)
T = 36.88 °C
