The phase diagram of CO2 has a melting curve that slopes up and to the right, in contrast to the phase diagram of water, which has a more conventional shape. It is impossible for liquid CO2 to exist at pressures lower than 5.11 atm because the triple point is 5.11 atm and 56.6 °C.
Due to the fact that ice is less thick than liquid water, the phase diagram of water has an odd melting point that drops with pressure. Carbon dioxide cannot exist as a liquid at atmospheric pressure, according to the phase diagram of the gas. Thus, gaseous carbon dioxide directly sublimes from solid carbon dioxide.
Learn more about solid carbon dioxide.
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1) Calculate the number of moles of O2 (g) in 300 cm^3 of gas at 298 k and 1 atm
Ideal gas equation: pV = nRT => n = pV / RT
R = 0.0821 atm*liter/K*mol
V = 300 cm^3 = 0.300 liter
T = 298 K
p = 1 atm
=> n = 1 atm * 0.300 liter / [ (0.0821 atm*liter /K*mol) * 298K] = 0.01226 mol
2) The reaction of a metal with O2(g) to form an ionic compound (with O2- ions) is of the type
X (+) + O2 (g) ---> X2O or
2 X(2+) + O2(g) ----> X2O2 = 2XO or
4X(3+) + 3O2(g) ---> 2X2O3
In the first case, 1 mol of metal react with 1 mol of O2(g); in the second case, 2 moles of metal react with 1 mol of O2(g); in the third, 4 moles of X react with 3 moles of O2(g)
So, lets probe those 3 cases.
3) Case 1: 1 mol of metal X / 1 mol O2(g) = x moles / 0.01226 mol
=> x = 0.01226 moles of metal X
Now you can calculate the atomic mass of the hypotethical metal:
1.15 grams / 0.01226 mol = 93.8 g / mol
That does not correspond to any of the metal with valence 1+
So, now probe the case 2.
4) Case 2:
2moles X metal / 1 mol O2(g) = x / 0.01226 mol
=> x = 2 * 0.01226 = 0.02452 mol
And the atomic mass of the metal is: 1.15 g / 0.02452 mol = 46.9 g/mol
That is similar to the atomic mass of titanium which is 47.9 g / mol and whose valece is 2+.
4) Case 3
4 mol meta X / 3 mol O2 = x / 0.01226 => x = 0.01226 * 4 / 3 = 0.01635
atomic mass = 1.15 g / 0.01635 mol = 70.33 g/mol
That does not correspond to any metal.
Conclusion: the identity of the metallic element could be titanium.
Answer : The correct option is, (D) 100 times the original content.
Explanation :
As we are given the pH of the solution change. Now we have to calculate the ratio of the hydronium ion concentration at pH = 5 and pH = 3
As we know that,
![pH=-\log [H_3O^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH_3O%5E%2B%5D)
The hydronium ion concentration at pH = 5.
![5=-\log [H_3O^+]](https://tex.z-dn.net/?f=5%3D-%5Clog%20%5BH_3O%5E%2B%5D)
![[H_3O^+]=1\times 10^{-5}M](https://tex.z-dn.net/?f=%5BH_3O%5E%2B%5D%3D1%5Ctimes%2010%5E%7B-5%7DM)
..............(1)
The hydronium ion concentration at pH = 3.
![3=-\log [H_3O^+]](https://tex.z-dn.net/?f=3%3D-%5Clog%20%5BH_3O%5E%2B%5D)
![[H_3O^+]=1\times 10^{-3}M](https://tex.z-dn.net/?f=%5BH_3O%5E%2B%5D%3D1%5Ctimes%2010%5E%7B-3%7DM)
................(2)
By dividing the equation 1 and 2 we get the ratio of the hydronium ion concentration.
![\frac{[H_3O^+]_{original}}{[H_3O^+]_{final}}=\frac{1\times 10^{-5}}{1\times 10^{-3}}=\frac{1}{100}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BH_3O%5E%2B%5D_%7Boriginal%7D%7D%7B%5BH_3O%5E%2B%5D_%7Bfinal%7D%7D%3D%5Cfrac%7B1%5Ctimes%2010%5E%7B-5%7D%7D%7B1%5Ctimes%2010%5E%7B-3%7D%7D%3D%5Cfrac%7B1%7D%7B100%7D)
![100\times [H_3O^+]_{original}=[H_3O^+]_{final}](https://tex.z-dn.net/?f=100%5Ctimes%20%5BH_3O%5E%2B%5D_%7Boriginal%7D%3D%5BH_3O%5E%2B%5D_%7Bfinal%7D)
From this we conclude that when the pH of a solution changes from a pH of 5 to a pH of 3, the hydronium ion concentration is 100 times the original content.
Hence, the correct option is, (D) 100 times the original content.
Based upon Max Planck's theory of black-body radiation, Einstein theorized that the energy in each quantum of light was equal to the frequency multiplied by a constant, later called Planck's constant. A photon above a threshold frequency has the required energy to eject a single electron, creating the observed effect.
For the first one, you have to find one that has both a metal and a nonmetal in it, plus potassium. Bonds between nonmetals are called covalent because they share electrons and a bond between a metal and a nonmetal is an ionic bond because they exchange electrons.
Potassium chloride is KCl. Only an ionic bond.
Potassium hydride is KH. Only an ionic bond.
Potassium nitrate is KNO3. There we go, that has a covalent bond between the nitrogen and oxygen, and an ionic bond between potassium and the nitrogen and oxygen.
For the second one, potassium chloride is the answer because the other three also have covalent bonds. Chloride is the only one that isn't a compound.
