Which acid could not be prepared by treating a Grignard reagent with CO2?
1 answer:
Answer:
4-oxopentanoic acid.
Explanation:
In this case, we must remember that the Grignard reaction is a reaction in which <u>carbanions</u> are produced. Carboanions have the ability to react with CO2 to generate a new C-C bond and a carboxylate ion. Finally, the acid medium will protonate the carboxylate to produce the <u>carboxylic acid group. </u>
The molecules that can follow the mechanism described above are the molecules: p-methylbenzoic acid, cyclopentane carboxylic acid and 3-methylbutanoic acid. (See figure 1)
In the case of <u>4-oxopentanoic acid</u>, the possible carbanion <u>will attack the carbonyl group</u> to generate a cyclic structure and an alcohol group (1-methylcyclopropan-1-ol). Therefore, this molecule cannot be produced by this reaction. (See figure 2)
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The masses of the components are obtained as;
- Sodium hydrogen carbonate = 3.51 g
- Sodium carbonate = 8.708 g
The term decomposition has to do with the breakdown of the given substance into its components. The components of sodium hydrogen carbonate could be identified as water vapor, carbon dioxide gas and sodium carbonate. Among these products that have been listed here, we can see that it is only the sodium carbonate that remains as a solid. The others are gases that move away from the system that is under study.
Now putting down the equation of the reaction, we have;
Now, the loss in mass must be due to the carbon dioxide and the water. Hence we obtain the loss in mass to be 10.000 g - 8.708 g = 1.292 g
Mass of sodium hydrogen carbonate = 2 * 88 g/mol * 1.292 g/62 g/mol
= 3.51 g
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