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bulgar [2K]
3 years ago
14

A student performs the reduction of 4-nitrobenzaldehyde (151.12 g/mol) with sodium borohydride (37.83 g/mol) in the presence of

ethanol. The student mixes 4.13 g of 4-nitrobenzaldehyde with 0.700 g of sodium borohydride and obtains 1.85 g of 4-nitrobenzyl alcohol (153.14 g/mol). What is the percent yield of this reaction
Chemistry
1 answer:
Leviafan [203]3 years ago
8 0

Answer:

65.4%

Explanation:

The redox reaction is a 1:1:1 reaction because the reagents suffer a double displacement reaction, and the substance that is substituted have the same charge (H+ and Br-), thus, we first need to know which of the reagents is the limiting.

Let's test the 4-nitrobenzaldehyde as the limiting. The mass needed for sodium borohydride (m) is the mass given of 4-nitrobenzaldehyde multiplied by the stoichiometric mass of sodium borohydride divided by the stoichiometric mass of 4-nitrobenzaldehyde. The stoichiometric mass is the number of moles in the stoichiometric representation (1:1:1) multiplied by the molar mass, so:

m = (4.13 * 37.83*1)/(151.12*1)

m = 1.034 g

So, the mass needed of the other reagent is larger than the mass that was given, so, it will be the limiting, and the stoichiometric calculus must be done with it.

The mass of the product that was expected is then:

m = (0.700*153.14*1)/(37.83*1)

m = 2.83 g

The percent yield is the mass that was formed divided by the expected mass, and then multiplied by 100%:

%yield = (1.85/2.83)*100%

%yield = 65.4%

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<h3>Answer:</h3>

28.52 seconds

<h3>Explanation:</h3>

Initial number of atoms of Nitrogen 12,000 atoms

Half-life = 7.13

Number of atoms after decay = 750 atoms

We are required to determine the time taken for the decay.

Note that half life is the time taken for a radioactive isotope to decay to a half of its original amount.

Using the formula;

Remaining amount = Initial amount × (1/2)^n , where n is the number of half lives

In our case;

750 atoms = 12,000 atoms × (1/2)^n

0.0625 = 0.5^n

n = log 0.0625 ÷ log 0.5

n = 4

But, 1 half life =7.13 seconds

Therefore;

Time taken = 7.13 seconds × 4

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Therefore, the time taken for 12,000 atoms of nitrogen to decay to 750 atoms is 28.52 seconds

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Answer:

Here's what I get  

Explanation:

I think this may be the equation you intended to write:

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The mole ratios are the ratios of the coefficients in the balanced equation.

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  3. C₃H₅(OH)₃:H₂O       = 1:3
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  5.           HCl:H₂O       = 3:3
  6.    C₃H₅Cl₃:H₂O       = 1:3

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