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taurus [48]
3 years ago
12

. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are

77.1 k/mole and −39.5 kJ/mole respectively, and the solubility product for Ag2S(s) is 8 10−51.
Chemistry
1 answer:
olga nikolaevna [1]3 years ago
8 0

<u>Answer:</u> The standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

K_{sp}\text{ of }Ag_2S=8\times 10^{-51}

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K

where,

\Delta G^o = standard Gibbs free energy = ?

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K = equilibrium constant or solubility product = 8\times 10^{-51}

Putting values in above equation, we get:

\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ

For the given chemical equation:

Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)

The equation used to calculate Gibbs free change is of a reaction is:  

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]

The equation for the Gibbs free energy change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]

We are given:

\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ

Putting values in above equation, we get:

285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol

Hence, the standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

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Using the equation, PV=nRT, you can solve this problem.

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We use the constant rate of <u>8.314</u> because we are using kilopascals in this problem.

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