A) polyester, hope it was quick enough
Answer:
Moving Across a Period
Moving from left to right across a period, the atomic radius decreases. The nucleus of the atom gains protons moving from left to right, increasing the positive charge of the nucleus and increasing the attractive force of the nucleus upon the electrons
Answer:

Explanation:
Since we have $N_A$ number of molecules in 22.4 L, in 15 L we have:
$\frac{15}{22.4}\times 6.023 \times 10^{23}$ molecules.
Answer : The rate law for formation of NOBr based on this mechanism is, ![\frac{k_1\times k_2}{k_1^-}[Br_2][NO]^2](https://tex.z-dn.net/?f=%5Cfrac%7Bk_1%5Ctimes%20k_2%7D%7Bk_1%5E-%7D%5BBr_2%5D%5BNO%5D%5E2)
Explanation :
The overall reaction is:

Rate law = ![k[Br_2][NO]^2](https://tex.z-dn.net/?f=k%5BBr_2%5D%5BNO%5D%5E2)
The first step of the overall reaction is:


Rate law 1 = ![k_1[Br_2][NO]](https://tex.z-dn.net/?f=k_1%5BBr_2%5D%5BNO%5D)
Rate law 2 = ![k_1^-[NOBr_2]](https://tex.z-dn.net/?f=k_1%5E-%5BNOBr_2%5D)
The second step of the overall reaction is:

Rate law 3 = ![k_2[NOBr_2][NO]](https://tex.z-dn.net/?f=k_2%5BNOBr_2%5D%5BNO%5D)
Now rate law of overall reaction can be obtained as follows.
We are multiplying rate law 1 and rate law 3 and dividing by rate law 2, we get:
Rate law = ![\frac{[k_1[Br_2][NO]]\times [k_2[NOBr_2][NO]]}{[k_1^-[NOBr_2]]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5Bk_1%5BBr_2%5D%5BNO%5D%5D%5Ctimes%20%5Bk_2%5BNOBr_2%5D%5BNO%5D%5D%7D%7B%5Bk_1%5E-%5BNOBr_2%5D%5D%7D)
Rate law = ![\frac{k_1\times k_2}{k_1^-}[Br_2][NO]^2](https://tex.z-dn.net/?f=%5Cfrac%7Bk_1%5Ctimes%20k_2%7D%7Bk_1%5E-%7D%5BBr_2%5D%5BNO%5D%5E2)
Rate law = ![k[Br_2][NO]^2](https://tex.z-dn.net/?f=k%5BBr_2%5D%5BNO%5D%5E2)
The rate law for formation of NOBr based on this mechanism is, ![\frac{k_1\times k_2}{k_1^-}[Br_2][NO]^2](https://tex.z-dn.net/?f=%5Cfrac%7Bk_1%5Ctimes%20k_2%7D%7Bk_1%5E-%7D%5BBr_2%5D%5BNO%5D%5E2)