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aleksklad [387]
3 years ago
10

Considering the volumes and the concentrations used in mixture 1, what percentage of the moles of H2O2 present have been consume

d during the timed reaction? Calculate the number of moles of H2O2 present initially and determine how many have reacted with iodide when the thiosulfate runs out. How does the I- concentration change during this same time?
Chemistry
1 answer:
Kisachek [45]3 years ago
3 0

Answer:

1 mol of H2O2 consumes 1 mol of S2O32, then 0.0005 mol of I- reacts with 0.00025 moles of H2O2

Thus, initial moles of H2O2 present in the mix is equal to 0.0102 moles.

Amount of moles of H2O2 that reacts with I- is equal to 0.00025 moles.

The amount of I ions that is oxidized by H2O2 and the iodine, I2 that is produced, is consumed by the S2O32- ions and are transformed into I ions. The amount of I ions that are consumed by H2O2 is equal to the amount of ion that is produced by S2O32-.

Explanation:

the total volume of the mixture is equal to:

Vmix = 75 + 30 + 25 + 5 + 5 + 10 = 150 mL

the moles of each species in the mix equals:

Na2S2O3 = 0.05 * 0.005 = 0.00025 moles

KI = 0.05 * 0.025 = 0.00125 moles

H2O2 = 1.02 * 0.01 = 0.0102 moles

the following equation shows the reaction between I2 and S2O32:

I2 + S2O32 = 2I- + S4O62-

The same way:

2I- + 2H+ + H2O2 = I2 + 2H2O

1 mol of H2O2 consumes 1 mol of S2O32, then 0.0005 mol of I- reacts with 0.00025 moles of H2O2

Thus, initial moles of H2O2 present in the mix is equal to 0.0102 moles.

Amount of moles of H2O2 that reacts with I- is equal to 0.00025 moles.

The amount of I ions that is oxidized by H2O2 and the iodine, I2 that is produced, is consumed by the S2O32- ions and are transformed into I ions. The amount of I ions that are consumed by H2O2 is equal to the amount of ion that is produced by S2O32-.

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B) Volumetric pipette – Glassware used to accurately transfer a small, single volume.

C) Beaker – Glassware best used when greater access to the contents is needed.

D) Buret – Glassware used to deliver a volume not known in advance.

E) Erlenmeyer flask – Glassware used to prevent splashing or evaporation.

F) Volumetric flask – Glassware used to make accurate solutions.

Explanation:

Graduated pipette – Glassware used to accurately transfer small volumes.

A graduated pipette is a pipette, which has a scale that shows its volume marked along the tube. It is used to transfer small volumes accurately.

Volumetric pipette – Glassware used to accurately transfer a small, single volume.

A volumetric pipette is a pipette, which has a ring like marking that is its calibrated volume. So it is used to transfer a single and small volume only. This pipette is used in volumetric analysis.

Beaker – Glassware best used when greater access to the contents is needed.

Beaker is the most widely used glassware in the laboratory. They are used to transfer large volume with less accuracy. They are of different sizes depends on the size of volumes ranging from 10 mL to 1000 mL.

Buret – Glassware used to deliver a volume not known in advance.

Buret is the most important glassware in the quantitative analysis. It has a glass tube with scale which measures the volume and a stopcock at one end from which the solvent is dispersed. It is used to measure the volume of the liquid during the titration in the quantitative analysis.

Erlenmeyer flask – Glassware used to prevent splashing or evaporation.

The most common names of Erlenmeyer flask are conical flask and titration flask. This flask has flat bottom, conical body and cylindrical neck which prevent splashing and evaporation. This flask is used in the titration process in the quantitative analysis. The solvent from the buret is delivered into the conical flask during the titration process.

Volumetric flask – Glassware used to make accurate solutions.

The volumetric flask is also an important glassware in the analytical laboratory. It is used to prepare standard solutions. It is a flask which has a ring like marking that is its calibrated volume. The mentioned volume of volumetric flask is calibrated to have accurate volume.

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