Answer:
a. 3-methylbutan-2-ol
b. 2-methylcyclohexan-1-ol
Explanation:
For this reaction, we must remember that the hydroboration is an <u>"anti-Markovnikov" reaction</u>. This means that the "OH" will be added at the <em>least substituted carbon of the double bond.</em>
In the case of <u>2-methyl-2-butene</u>, the double bond is between carbons 2 and 3. Carbon 2 has two bonds with two methyls and carbon 3 is attached to 1 carbon. Therefore <u>the "OH" will be added to carbon three</u> producing <u>3-methylbutan-2-ol</u>.
For 1-methylcyclohexene, the double bond is between carbons 1 and 2. Carbon 1 is attached to two carbons (carbons 6 and 7) and carbon 2 is attached to one carbon (carbon 3). Therefore<u> the "OH" will be added to carbon 2</u> producing <u>2-methylcyclohexan-1-ol</u>.
See figure 1
I hope it helps!
Answer:
Explanation:
The result will be affected.
The mass of KHP weighed out was used to calculate the moles of KHP weighed out (moles = mass/molar mass).
Not all the sample is actually KHP if the KHP is a little moist, so when mass was used to determine the moles of KHP, a higher number of moles than what is actually present would be obtained (because some of that mass was not KHP but it was assumed to be so. Therefore, there is actually a less present number of moles than the certain number that was thought of.
During the titration, NaOH reacts in a 1:1 ratio with KHP. So it was determined that there was the same number of moles of NaOH was the volume used as there were KHP in the mass that was weighed out. Since there was an overestimation in the moles of KHP, then there also would be an overestimation in the number of moles of NaOH.
Thus, NaOH will appear at a higher concentration than it actually is.
Answer:
1,45 mL
Explanation:
The Grignard reaction is a very important organometallic chemical reaction where the Grignard reagent ( alkyl, vinyl, or aryl-magnesium halides) acts as nucleophile in order to the formation of Carbon-Carbon bonds.
In the problem, the phenylmagnesium chloride is the grignard reagent. The volume of 2.0 M phenylmagnesium chloride solution you need to add 2.9 mmol is:
2,9 mmol × 
= <em>1,45 mL</em>
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I hope it helps!
Answer:
CH₂ ; 67.1 %
Explanation:
To determine the empirical formula we need to find what the mole ratio is in whole numbers of the atoms in the compound. To do that we will first need the atomic weights of C and H and then perform our calculation
Assume 100 grams of the compound.
# mol C = 85.7 g / 12.01 g/mol = 7.14 mol
# mol H = 14.3 g / 1.008 g/mol = 14.19 mol
The proportion is 14.9 mol H/ 7.14 mol C = 2 mol H/ 1 mol C
So the empirical formula is CH₂
For the second part we will need to first calculate the theoretical yield for the 12.03 g NaBH₄ reacted and then calculate the percent yield given the 0.295 g B₂H₆ produced.
We need to calculate the moles of NaBH₄ ( M.W = 37.83 g/mol )
1.203 g NaBH₄ / 37.83 g/mol = 0.0318 mol
Theoretical yield from balanced chemical equation:
0.0318 mol NaBH₄ x 1 mol B₂H₆ / mol NaBH₄ = 0.0159 mol B₂H₆
Theoretical mass yield B₂H₆ = 0.0159 mol x 27.66 g/ mol = 0.440 g
% yield = 0.295 g/ 0.440 g x 100 = 67.1 %
Answer:
The answer is 5. Compound
