<span>Non-stoichiometric defects are </span>compounds which contain the combining elements in a ratio different from that required by their stoichiometric formula. The solids with metal excess <span>defect </span>contain metal in excess to the stoichiometric ratio. Such defect is caused due to either of the following reasons:
1. <span>Metal excess Defect due to Anionic Vacancies:
In this, </span>negative ions may be missing from their lattice sites leaving holes in
which the electrons remain entrapped to maintain the electrical
neutrality.
2. Metal excess defect due to the presence of extra cations at interstitial sites:
In this case, there are extra positive ions occupying interstitial
sites and the electrons in another interstitial sites to maintain
electrical neutrality. The defect may be visualized as the loss of
non-metal atoms which leave their electrons behind. The excess metal
ions occupy interstitial positions.
Answer:
Reactions in which a multiple bond between two atoms becomes partly or fully saturated by covalent attachments... A typical addition reaction may be illustrated by the hydrochlorination of propene (an alkene), for which the equation is CH3CH = CH2 + HCl → CH3C+HCH3 + Cl− → CH3CHClCH3.
Explanation:
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The
balanced reaction would be written as:
<span>
C7H6O3 + C4H6O3--->C9H8O4 + HC2H3O2
To determine the percent yield, we need to first
determine the theoretical yield if the reaction were to proceed completely.
Then, we divide the actual yield that is given to the theoretical yield times
100 percent. The limiting reactant from the reaction would be salicylic acid.
We do as follows:
<span>Theoretical yield: 50.05 g C7H6O3 ( 1 mol /
138.21 g ) ( 1 mol C9H8O4 / 1 mol C7H6O3 ) ( 180.157 g / mol ) = 65.24 g C9H8O4 should be produced
Percent yield = 55.45 / 65.24 x 100 = 84.99%
<span>
Therefore, the percent yield for the given amount of salicylic acid is 84.99%
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Ammonia yields nitric oxide and water in the presence of oxygen. The mass of nitric acid that will be produced from 6.40 gm of oxygen is 4.8 grams.
<h3>What is mass?</h3>
Mass is the product of the moles of the substance and its molar mass. it is given as,
The balanced chemical reaction is shown as:
Moles of oxygen are calculated by mass, 6.40 gm as,
From the reaction, the molar ratio of nitric oxide to oxygen is 4: 5 and is used to calculate the moles of nitric oxide as,
0.16 moles and molar mass, 30 of nitric oxide is used to calculate the mass as,
Therefore, 4.8 grams of nitric oxide will be produced.
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