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Dovator [93]
3 years ago
12

Write the balanced equation for the reaction of aqueous Pb ( ClO 3 ) 2 with aqueous NaI . Include phases. chemical equation: Wha

t mass of precipitate will form if 1.50 L of highly concentrated Pb ( ClO 3 ) 2 is mixed with 0.200 L 0.300 M NaI
Chemistry
1 answer:
aleksandr82 [10.1K]3 years ago
6 0

<u>Answer:</u> The mass of precipitate (lead (II) iodide) that will form is 13.83 grams

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Molarity of NaI solution = 0.300 M

Volume of solution = 0.200 L

Putting values in above equation, we get:

0.300M=\frac{\text{Moles of NaI}}{0.200L}\\\\\text{Moles of NaI}=(0.300mol/L\times 0.200L)=0.06mol

The balanced chemical equation for the reaction of lead chlorate and sodium iodide follows:

Pb(ClO_3)_2(aq.)+2NaI(aq.)\rightarrow PbI_2(s)+2NaClO_3(aq.)

By Stoichiometry of the reaction:

2 moles of NaI produces 1 mole of lead (II) iodide

So, 0.06 moles of NaI will produce = \frac{1}{2}\times 0.06=0.03mol of lead (II) iodide

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Moles of lead (II) iodide = 0.03 moles

Molar mass of lead (II) iodide = 461.1 g/mol

Putting values in above equation, we get:

0.03mol=\frac{\text{Mass of lead (II) iodide}}{461.1g/mol}\\\\\text{Mass of lead (II) iodide}=(0.03mol\times 461.1g/mol)=13.83g

Hence, the mass of precipitate (lead (II) iodide) that will form is 13.83 grams

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2 years ago
A single-effect evaporator is concentrating a feed of 9072 kg/h of a 10 wt % solution of NaOH in water at temperature of 288.8 K
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Answer:

a) steam used = 8440 kg/hr

b)  Because as per calculation done in a), Steam is sufficient to evaporate 7257.6 kg/hr water from feed. Since feed is less than this amount, therefore whole water will be evaporated and 100% solid product will be obtained in bottom collection

Explanation:

Saturated steam pressure = 42KPag=1.42 bar

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Process side pressure = 20 Kpaa = .2 bar

Water latent heat at this Pressue = 2360 KJ/kg

Water boiling Point at this Pressure =60 C

Feed Inlet temperature = 15.6 C

Total Heat required = Heat required to rise feed temperature from 15.6 to 60 degree C + Evaporation of water to concentrate the feed

Total Water evaporation required = 9072*(100-10)/100-9072*.1/.5*.5=7257.6 Kg/hr

Specific heat of feed assumed = 4.2 KJ/kg/K

=> Total heat required = 9072*4.2*(60-15.6)+7257.6*2360=18819682 KJ/hr

LMTD = ((110-60)-(110-15.6))/LN((110-60)/(110-15.6))=69.8 C

U, Overall Heat transfer coefficient = 1988 W/m2/K

Total heat required = U*A*LMTD

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Energy required to condense vaporised feed = 7257.6*2360=17127936 KJ/hr

=> Steam efficiency = (18819682-17127936)/18819682=9%

b) Because as per calculation done in a), Steam is sufficient to evaporate 7257.6 kg/hr water from feed. Since feed is less than this amount, therefore whole water will be evaporated and 100% solid product will be obtained in bottom collection

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