Almost. treating an acyl chloride with a grignard reagent tends to form (via two steps) an alcohol. what reagent forms the keton
e product but does not react with the ketone?
1 answer:
Reaction of Acyl Halides with Grignard reagent results in the formation of Ketones in first step. While in second step reaction of Grignard reagent with Ketones results in the formation of Tertiary Alcohols.
If you want to stop the reaction at Ketone stage then you are required to use another mild reactive organometallic compound. In our case we will use Organocuprates. Organocuprates are also known as Gilman Reagents. These reagents does not add to ketones, aldehydes and esters but they can add to acid halides to produce Ketones.
If you want to stop the reaction at Ketone stage then you are required to use another mild reactive organometallic compound. In our case we will use Organocuprates. Organocuprates are also known as Gilman Reagents. These reagents does not add to ketones, aldehydes and esters but they can add to acid halides to produce Ketones.
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The molar extinction coefficient is 15,200 .
The formula to be used to calculate molar extinction coefficient is -
A = ξcl, where A represents absorption, ξ refers molar extinction coefficient, c refers to concentration and l represents length.
The given values are in required units, hence, there is no need to convert them. Directly keeping the values in formula to find the value of molar extinction coefficient.
Rewriting the formula as per molar extinction coefficient -
ξ =
ξ =
Performing multiplication in denominator to find the value of molar extinction coefficient
ξ =
Performing division to find the value of molar extinction coefficient
ξ = 15,200
Hence, the molar extinction coefficient is 15,200 .
Learn more about molar extinction coefficient -
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