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kogti [31]
3 years ago
14

Which of the following is an acceptable IUPAC name?(A) 3,6-dimethylheptane (B) 2-ethyl-3-methylheptane (C) 5-methyl-3-ethylhepta

ne (D) 4-ethyl-4-methylheptaneD

Chemistry
1 answer:
bearhunter [10]3 years ago
3 0

Answer:

D) 4-ethyl-4-methylheptane

Explanation:

The rules for naming of alkanes with substituents.

1. The carbon chain with the maximum number of carbon atoms must be selected as a parent chain.

2.Numbering should be done in such a way that each substituent gets the least number.

3. Substituents whose name comes before the another substituents's name in the English alphabet is written first.

4. Substituents are written first with their location in the chain and the name of the parent chain is done. Numbers are separated from numbers by comma and numbers are separated from letters by using hyphen.

Considering (a) 3,6-dimethylheptane

<u>Violation of Rule - 2 mentioned above</u>

The numbering of the parent chain is not done in a right way. Numbering must be done such that each substituent gets the least number. So, The correct name is 2,5-dimethylheptane

Considering (b) 2-ethyl-3-methylheptane

<u>Violation of Rule - 1 mentioned above.</u>

The carbon chain with the maximum number of carbon atoms must be selected as a parent chain. The parent chain selected is of 7 carbon atoms but the parent chain is of 8 carbon atoms. So, The correct name is 3,4-dimethyloctane

Considering (c) 5-methyl-3-ethylheptane

<u>Violation of Rule - 3 mentioned above.</u>

'e' comes before 'm' . So, ethyl- is written first than methyl- . So, The correct name is 3,6-dimethyloctane

Considering (d) 4-ethyl-4-methylheptane

<u>This is a IUPAC name and following all the rules mentioned above.</u>

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What must be the molarity of an aqueous solution of trimethylamine, (ch3)3n, if it has a ph = 11.20? (ch3)3n+h2o⇌(ch3)3nh++oh−kb
Stolb23 [73]

0.040 mol / dm³. (2 sig. fig.)

<h3>Explanation</h3>

(\text{CH}_3)_3\text{N} in this question acts as a weak base. As seen in the equation in the question, (\text{CH}_3)_3\text{N} produces \text{OH}^{-} rather than \text{H}^{+} when it dissolves in water. The concentration of \text{OH}^{-} will likely be more useful than that of \text{H}^{+} for the calculations here.

Finding the value of [\text{OH}^{-}] from pH:

Assume that \text{pK}_w = 14,

\begin{array}{ll}\text{pOH} = \text{pK}_w - \text{pH} \\ \phantom{\text{pOH}} = 14 - 11.20 &\text{True only under room temperature where }\text{pK}_w = 14 \\\phantom{\text{pOH}}= 2.80\end{array}.

[\text{OH}^{-}] =10^{-\text{pOH}} =10^{-2.80} = 1.59\;\text{mol}\cdot\text{dm}^{-3}.

Solve for [(\text{CH}_3)_3\text{N}]_\text{initial}:

\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}

Note that water isn't part of this expression.

The value of Kb is quite small. The change in (\text{CH}_3)_3\text{N} is nearly negligible once it dissolves. In other words,

[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}.

Also, for each mole of \text{OH}^{-} produced, one mole of (\text{CH}_3)_3\text{NH}^{+} was also produced. The solution started with a small amount of either species. As a result,

[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}.

\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3},

[(\text{CH}_3)_3\text{N}]_\textbf{initial} =\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{\text{K}_b},

[(\text{CH}_3)_3\text{N}]_\text{initial} =\dfrac{(1.58\times10^{-3})^{2}}{6.3\times10^{-5}} = 0.040\;\text{mol}\cdot\text{dm}^{-3}.

8 0
4 years ago
You have 45.2 liters of SO2. This would be equal to
Andreas93 [3]

Answer:

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4 0
3 years ago
PLEASE HELP!!!
trasher [3.6K]

Answer:

(a) oxygen

(b) 154g (to 3sf)

(c) 79.9% (to 3sf)

Explanation:

mass (g) = moles × Mr/Ar

note: eqn means chemical equation

(a)

moles of P = 84.1 ÷ 30.973 = 2.7152 moles

moles of O2 = 85÷2(16) = 2.65625 moles

Assuming all the moles of P is used up,

moles of O2 / moles of phosphorus = 5/4 (according to balanced chemical eqn)

moles of O2 required = 5/4 × 2.7152moles = 3.394 moles (more than supplied which is 2.65625moles)

therefore there is insufficient moles of O2 and the limiting reactant is oxygen.

(b)

moles of P2O5 produced

= 2/5 (according to eqn) × 2.7152

= 1.08608moles

mass of P2O5 produced

= 1.08608 × [ 2(30.973) + 5(16) ]

= 154.164g

= approx. 154g to 3 sig. fig.

(c)

% yield = actual/theoretical yield × 100%

= 123/154 × 100%

= 79.870%

= approx. 79.9% (to 3sf)

4 0
3 years ago
Construct an argument for or against the immediate introduction of fuel-cell cars. Include likely points of objection from those
ryzh [129]

Answer:

Explanation:

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Hydrocarbons are the organic compounds which are derived mostly from the crude oil. They are usually composed of Hydrogen and Carbon.

Fuel cell cars are much more better than the regular vehicles running on hydrocarbon in so many ways especially environmentally.

Listed below are some of the advantages of fuel cell cars over the regular vehicles

Fuel cells have a higher efficiency than diesel or gas engines.

Most fuel cells operate silently, compared to internal combustion engines. They are therefore ideally suited for use within buildings such as hospitals.

Fuel cells can eliminate pollution caused by burning fossil fuels; for hydrogen fuelled fuel cells, the only by-product at point of use is water.

If the hydrogen comes from the electrolysis of water driven by renewable energy, then using fuel cells eliminates greenhouse gases over the whole cycle.

Fuel cells do not need conventional fuels such as oil or gas and can therefore reduce economic dependence on oil producing countries, creating greater energy security for the user nation.

Since hydrogen can be produced anywhere where there is water and a source of power, generation of fuel can be distributed and does not have to be grid-dependent.

The use of stationary fuel cells to generate power at the point of use allows for a decentralised power grid that is potentially more stable.

8 0
4 years ago
Read 2 more answers
Why is a crystal of Strontium chloride described as an extended structure?
olchik [2.2K]

Answer:

Explanation:

Chloride is described as an extended structure because its atoms are arranged following an endless repeating pattern and are of distinct ratio

Crystals and polymers mostly form extended structures as seen in the formation of sodium chloride whereby the ions in the compound are arranged following a repeating pattern. ( i.e. has a giant ionic structure ).

Chloride is a considered an extended structure because in sodium chloride it forms an unending repeated pattern of ions which makes it a perfect example of an extended structure.

Hence we can conclude that Chloride can be described as an extended structure because its atoms are arranged following a repeating pattern and are of distinct ratio.

5 0
3 years ago
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