The tert-butyl chloride in ethanol would surely react faster than the solvolysis of 1-chloro-2,2-dimethyl propane. It is known that both reactions are under the SN2 category so it would be hard for these reactions to occur. However, SN1 reactions are possible because of the ethanol which is a polar solvent. Both would form carbocations but tert-butyl chloride forms a more stable carbocation while the 1-chloro-2,2-dimethyl propane forms a primary carbocation only.
Answer: (A) It appears as a reactant in the net chemical reaction
Explanation:
A catalyst is A substance that speed up the chemical reaction without its self being consumed in the reactants or the products.It does this by lowering the activation energy of the reaction by speeding up the rate of reaction.
Mass of methane takne = 1.5g
moles of methane used = masss / molar mass = 1.5 / 16 = 0.094 moles
mass of water = 1000 g
Initial temperature of water = 25 C
final temperature = 37 C
specific heat of water = 4.184 J /g C
1) Heat absorbed by water = q =m• C• ΔT = 1000 X 4.184 x (37-25) = 50208 Joules
2) Heat absorbed by calorimeter = Heat capacity X ΔT = 695 X (37-25) = 8340 J
3) Total heat of combustion = heat absorbed by water + calorimeter = 50208 + 8340 = 58548 Joules
This heat is released by 0.094 moles of methane
So heat released by one mole of methane =
- 622851.06 Joules = 622.85 kJ / mole
4) standard enthalpy of combustion = -882 kJ / mole
Error = (882-622.85) X 100 / 882 = 24.84 %
Answer:
- Initial: forward rate > reverse rate
- Equilibrium: forward rate = reverse rate
Explanation:
2NO₂(g) → N₂O₄(g) Kc=4.7
The definition of <em>equilibrium</em> is when the forward rate and the reverse rate are <em>equal</em>.
Because in the initial state there's only NO₂, there's no possibility for the reverse reaction (from N₂O₄ to NO₂). Thus the forward rate will be larger than the reverse rate.