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madam [21]
3 years ago
7

| A solution containing 4.48 ppm KMnO4 exhibits

Chemistry
1 answer:
Artist 52 [7]3 years ago
6 0

Answer:

Molar absorptivity or molar extinction co-effecient = 2120.14 cm⁻¹M⁻¹

Explanation:

First convert Concentration from ppm inM or mol/l

⇒ Molar mass of KMnO₄ = 158.03 g

⇒ 4.48 ppm = 4.48 mg/l = 4.48 x 10⁻³ g/l

⇒ Molarity = \frac{4.48 X10^{-3} }{158.03X 1(lit)} = 2.83 x 10⁻⁵ molar

Absorbance (A) = - log(T)     ( T = % transmittance)

                          = - log(0.859)

                          = 0.06

According to Lambert Beer's law

     

                 ε = \frac{A}{C X l}

      or,      ε = \frac{0.06}{2.83 X 10^{-5}X1 cm }

      or,      ε = 2120.14 cm⁻¹M⁻¹

Where

    ε = Molar absorptivity

    A = absorbance

    C = Molar concentration of KMnO₄ solution

     l = length  

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