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3 years ago

Which of the following is the best definition of Hess' Law?

1 answer:

7 0

Hess' Law can best be described as A. Heat evolved in a given process can be expressed as the sum of the heats of several processes that, when added, yield the process of interest.

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Many power plants produce energy by burning carbon-based fuels, which also produces carbon dioxide. Carbon dioxide is a greenhou

RUDIKE [14]

Answer:

a) 2.541 mol/MJ;

b) 1.124 mol/MJ;

c) 0.4354 mol/MJ;

d) 0.1835 mol/MJ

Explanation:

The enthalpy of formation (ΔH°f) is the enthalpy of a reaction to form a compound by its constituents. For CO₂, ΔH°f = - 393.5 kJ/mol.

The enthalpy of a reaction is the sum of the enthalpy of the products (each one multiplied by the number of moles) less the sum of the enthalpy of the reactants (each one multiplied by the number of moles). The ΔH°f for simple substances (with one atom) is 0. The combustion is the reaction between the fuel and the oxygen.

a) The combution reaction is:

C(s) + O₂(g) → CO₂(g)

ΔH°rxn = -393.5 kJ/mol = -393.5x10⁻³ MJ/mol

Number of moles per MJ released: 1/|ΔH°rxn|

n = 1/(393.5x10⁻³) = 2.541 mol/MJ

b) The combustion reaction is:

CH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(l)

H₂O is in the liquid state because it's at 1 atm and 25ºC.

ΔH°f, H₂O(l) = -285.3 kJ/mol

ΔH°f, O₂(g) = 0

ΔH°f, CH₄(g) = -74.8 kJ/mol

ΔH°rxn = [2*(-285.3 ) + 1*(-393.5)] - [1*(-74.8)]

ΔH°rxn = -889.3 kJ/mol = -889.3x10⁻³ MJ/mol

n = 1/889.3x10⁻³ = 1.124 mol/MJ

c) C₃H₈(g) + 10O₂(g) → 3CO₂(g) + 4H₂O(l)

ΔH°f,C₃H₈(g) = -25.2 kJ/mol

ΔH°rxn = [4*(-285.3) + 3*(-393.5)] - [1*(-25.2)]

ΔH°rxn = -2,296.5 kJ/mol = -2.2965 MJ/mol

n = 1/2.2965 = 0.4354 mol/MJ

d) C₈H₁₈(l) + (25/2)O₂(g) → 8CO₂(g) + 9H₂O(l)

ΔH°f, C₈H₁₈(l) = -250.1 kJ/mol

ΔH°rxn = [9*(-283.5) + 8*(-393.5)] - [1*(-250.1)]

ΔH°rxn = -5,449.4 kJ/mol = -5.4494 MJ/mol

n = 1/5.4494 = 0.1835 mol/MJ

4 0

2 years ago

If 200 g of water is heated from 20 C to 40 C, then what is the heat added in kilocalories (same as food calories)?

Maslowich

Answer: 4Kcal

Explanation:

H= mcø

M=200g

C= 1 cal/g/°c

Ø= 40-20=20°c

H= 200*1*20= 4000calories= 4Kcal

8 0

2 years ago

Which of these orbital filling diagrams are drawn correctly? (select all that apply)

shutvik [7]

Answer:

Explanation:

The option A is draw well about sha

5 0

2 years ago

An analytical chemist is titrating of a solution of propionic acid with a solution of 224.9 ml of a 0.6100M solution of propioni

Svetllana [295]

Answer: The pH of acid solution is 4.58

Explanation:

To calculate the number of moles for given molarity, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in mL)}}$ .....(1)

For KOH:

Molarity of KOH solution = 1.1000 M

Volume of solution = 41.04 mL

Putting values in equation 1, we get:

$1.1000M=\frac{\text{Moles of KOH}\times 1000}{41.04}\\\\\text{Moles of KOH}=\frac{1.1000\times 41.04}{1000}=0.04514mol$

For propanoic acid:

Molarity of propanoic acid solution = 0.6100 M

Volume of solution = 224.9 mL

Putting values in equation 1, we get:

$0.6100M=\frac{\text{Moles of propanoic acid}\times 1000}{224.9}\\\\\text{Moles of propanoic acid}=\frac{0.6100\times 224.9}{1000}=0.1372mol$

The chemical reaction for propanoic acid and KOH follows the equation:

$C_2H_5COOH+KOH\rightarrow C_2H_5COOK+H_2O$

Initial: 0.1372 0.04514

Final: 0.09206 - 0.04514

Total volume of solution = [224.9 + 41.04] mL = 265.94 mL = 0.26594 L (Conversion factor: 1 L = 1000 mL)

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

$pH=pK_a+\log(\frac{[\text{salt}]}{[acid]})$

$pH=pK_a+\log(\frac{[C_2H_5COOK]}{[C_2H_5COOH]})$

We are given:

$pK_a$ = negative logarithm of acid dissociation constant of propanoic acid = 4.89

$[C_2H_5COOK]=\frac{0.04514}{0.26594}$

$[C_2H_5COOH]=\frac{0.09206}{0.26594}$

pH = ?

Putting values in above equation, we get:

$pH=4.89+\log(\frac{(0.04514/0.26594)}{(0.09206/0.26594)})\\\\pH=4.58$

Hence, the pH of acid solution is 4.58

7 0

3 years ago

Disponemos de 514,5 g de ácido sulfúrico (H2SO4

EleoNora [17]

Answer:

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Explanation:

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8 0

3 years ago