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Marina86 [1]
3 years ago
6

Carbon is allowed to diffuse through a steel plate 15 mm thick. The concentrations of carbon at the two faces are 0.65 and 0.30

kg C/m3 Fe, which are maintained constant. If the preexponential and activation energy are 6.2 x 10-7 m2/s and 80,000 J/mol, respectively, compute the temperature at which the diffusion flux is 1.43 x 10-9kg/m2-s.
Physics
1 answer:
beks73 [17]3 years ago
4 0

Answer:

T=575.16K

Explanation:

To solve the problem we proceed to use the 1 law of diffusion of flow,

Here,

J=-D\frac{\Delta C}{\Delta x}

\Delta C is the rate in concentration

\Delta xis the rate in thickness

D is the diffusion coefficient, where,

D= D_0 exp(\frac{Q_d}{RT})

Replacing D in the first law,

J=-(D_0 exp(\frac{-Q_D}{RT}))\frac{\Delta }{\Delta x}

clearing T,

T=\frac{Q_d}{R*ln(\frac{J*\Delta x}{D_0*\Delta C})}

Replacing our values

T=-\frac{80000}{8.31*ln(\frac{(6.2*10^{-7})(-15*10^{-3})}{(1.43*10^{-9})(0.65-0.30)})}

T=-\frac{80000}{-138.09}

T=575.16K

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Answer:

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Explanation:

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E^{\circ}(\text{cell}) = E^{\circ}(\text{cathode}) - E^{\circ}(\text{anode}).

There are two half-reactions in this question. \rm Cu^{2+} + 2\,e^{-} \rightleftharpoons Cu and \rm Pb^{2+} + 2\,e^{-} \rightleftharpoons Pb. Either could be the cathode (while the other acts as the anode.) However, for the reaction to be spontaneous, the value of E^{\circ}(\text{cell}) should be positive.

In this case, E^{\circ}(\text{cell}) is positive only if \rm Cu^{2+} + 2\,e^{-} \rightleftharpoons Cu is the reaction takes place at the cathode. The net reaction would be

\rm Cu^{2+} + Pb \to Cu + Pb^{2+}.

Its cell potential would be equal to 0.339 - (-0.130) = \rm 0.469\; V.

The maximum amount of electrical energy possible (under standard conditions) is equal to the free energy of this reaction:

\Delta G^{\circ} = n \cdot F \cdot E^{\circ} (\text{cell}),

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\begin{aligned}\Delta G^{\circ} &= n \cdot F \cdot E^{\circ} (\text{cell})\cr &= 2\times 96485.33212 \times (0.339 - (-0.130)) \cr &\approx 9.0 \times 10^{4} \; \rm J \cr &= 90\; \rm kJ\end{aligned}.

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e force acting between two charged particles A and B is 5.2 × 10-5 newtons. Charges A and B are 2.4 × 10-2 meters apart. If the
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