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Paraphin [41]
2 years ago
9

Construct a three-step synthesis of 1,2-epoxycyclopentane from cyclopentanol by dragging the appropriate formulas into the bins.

Note that each bin will hold only one item, and not all of the given reagents or structures will be used.

Chemistry
1 answer:
vladimir2022 [97]2 years ago
8 0

Answer:

(1) Bromination, (2) E2 elimination and (3) epoxidation

Explanation:

  • In the first step, -OH group in cyclopentanol is replaced by more facile leaving group Br by treating cyclopentanol with PBr_{3}
  • In the second step, E2 elimination in presence of strong base e.g. NaOEt/EtOH produce cyclopentene
  • In the third step, treatment of cyclopentene with mCPBA produces 1,2-epoxycyclopentane
  • Full reaction scheme has been shown below

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A blacksmith heated an iron bar to 1445 °C. The blacksmith then tempered the metal by dropping it into 42,800 mL of
Wittaler [7]

Answer:

6626 g

Explanation:

Given that:

Density of water = 1.00 g/ml, volume of water = 42800 ml.

Since density = mass/ volume

mass of water = volume of water * density of water = 42800 ml * 1 g/ml = 42800 g

Initial temperature of water = 22°C and final temperature of water = 45°C.

specific heat capacity for water = 4.184 J/g°C

ΔT water = 45 - 22 = 23°C

For iron:

mass = m,  

specific heat capacity for iron  = 0.444 J/g°C

Initial temperature of iron = 1445°C and final temperature of water = 45°C.

ΔT iron = 45 - 1445 = -1400°C

Quantity of heat (Q) to raised the temperature of a body is given as:

Q = mCΔT

The quantity of heat required to raise the temperature of water is equal to the temperature loss by the iron.

Q water (gain) + Q iron (loss) = 0

Q water = - Q iron

42800 g ×  4.184 J/g°C × 23°C = -m × 0.444 J/g°C × -1400°C

m = 4118729.6/621.6

m = 6626 g

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