Construct a three-step synthesis of 1,2-epoxycyclopentane from cyclopentanol by dragging the appropriate formulas into the bins.
Note that each bin will hold only one item, and not all of the given reagents or structures will be used.
1 answer:
Answer:
(1) Bromination, (2) E2 elimination and (3) epoxidation
Explanation:
- In the first step, -OH group in cyclopentanol is replaced by more facile leaving group Br by treating cyclopentanol with
- In the second step, E2 elimination in presence of strong base e.g. NaOEt/EtOH produce cyclopentene
- In the third step, treatment of cyclopentene with mCPBA produces 1,2-epoxycyclopentane
- Full reaction scheme has been shown below
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Answer:
1 gramo de metano aporta 50.125 kilojoules.
1 gramo de metano aporta 48.246 kilojoules.
Explanation:
La cantidad de energía liberada por la combustión de una unidad de masa del hidrocarburo (), en kilojoules por mol, es igual a la cantidad de energía liberada por mol de compuesto (
), en kilojoules por mol, dividido por su masa molar (
), en gramos por mol:
(1)
A continuación, analizamos cada caso:
Metano
1 gramo de metano aporta 50.125 kilojoules.
Octano
1 gramo de metano aporta 48.246 kilojoules.