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Ganezh [65]
3 years ago
9

Estimate the enthalpy change for the combustion of one mole of acetylene, C2H2, to form carbon dioxide and water vapor. BE(C?H)

= 456 kJ/mol) BE(C?C) = 962 kJ/mol BE(O=O) = 499 kJ/mol BE(C=O) = 802 kJ/mol BE(O?H) = 462 kJ/molAnswer choices:A. +653 kJ/molB. ?155 kJ/molC. +1010 kJ/molD. ?1759 kJ/molE. ?1010 kJ/mol
Chemistry
1 answer:
tia_tia [17]3 years ago
4 0

Answer:

ΔH rxn =  -1010 kJ/molC₂H₂

Explanation:

To obtain the enthalpy change for a reaction from bond energies what we do is to make an inventory of the bonds broken and formed for the balanced chemical reaction:

C₂H₂ + 5/2O₂   ⇒   2CO₂ + H₂O

Bond Broken                                    Bonds Formed

2 C-H + 1 C≡C + 5/2 O=O                4C=O + 2 H-O

Enthalpy bonds broken:

2 mol (456 kJ/mol)+ 1 mol (962 kJ/mol) + 5/2 mol (499 kJ/mol)  =  3121.5 kJ

Enthalpy bond formed:

4 mol (802 kJ/mol) + 2 mol (462 kJ/mol) = 4132.0 kJ

ΔH rxn = H broken - H formed =  3121.5 kJ - 4132.0 kJ = - 1010  kJ (per mol C₂H₂ )

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A single penny has a mass of 2.5 g. Abbie and James each measure the mass of a penny multiple times. Which statement about these
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The question is missing the data sets.

This is the complete question:

A single penny has a mass of 2.5 g. Abbie and James each measure the mass of a penny multiple times. Which statement about these data sets is true? 

O Abbie's measurements are both more accurate and more precise than James'.

O Abbie's measurements are more accurate, but less precise, than James'. 

O Abbie's measurements are more precise, but less accurate, than James'. 

O Abbie’s measurements are both less accurate and less precise than James'. 

Penny masses (g)

Abbie’s data                                        

2.5, 2.4, 2.3, 2.4, 2.5, 2.6, 2.6 

James’ data


2.4, 3.0, 3.3, 2.2, 2.9, 3.8, 2.9

Answer: first option, Abbie's measurements are both more accurate and more precise than James'.

Explanation:


1) To answer this question, you first must understand the difference between precision and accuracy.

<span>Accuracy is how close the data are to the true or accepted value.
</span>

<span>Precision is how close are the data among them, this is the reproducibility of the values.</span>

Then, you can measure the accuracy by comparing the means (averages) with the actual mass of a penny 2.5 g.

And you measure the precision by comparing a measure of spread, as it can be the standard deviation.

2) These are the calculations:

Abbie’s data                      
                 
Average: ∑ of the values / number of values 

Average = [2.5 + 2.4 + 2.3 + 2.4 + 2.5 + 2.6 + 2.6 ] / 7 = 2.47 ≈ 2.5

Standard deviation: √  [ ∑ (x - mean)² / (n - 1) ] = 0.11


James’ data


Average = [2.4 + 3.0 + 3.3 + 2.2 + 2.9 + 3.8 + 2.9] / 7 = 2.56 ≈ 2.6


Standard deviation = 0.53

3) Conclusions:

1) The average of Abbie's data are closer to the accepted value 2.5g, so they are more accurate.

2) The standard deviation of Abbie's data is smaller than that of Jame's data, so the Abbie's data are more precise.
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