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ad-work [718]
3 years ago
7

The vapor pressure of liquid chloroform, CHCl3, is 100. mm Hg at 283 K. A 0.380 g sample of liquid CHCl3 is placed in a closed,

evacuated 380. mL container at a temperature of 283 K.
Assuming that the temperature remains constant, will all of the liquid evaporate? _____yes/no
What will the pressure in the container be when equilibrium is reached? _______mm Hg
Chemistry
1 answer:
Katyanochek1 [597]3 years ago
4 0

Answer:

a

No

b

100 mm Hg

Explanation:

From the question we are told that

The vapor pressure of CHCl3, is P = 100 \  mmHg =  \frac{100}{760}=  0.13156 \ atm

The temperature of CHCl3 is T  =  283 \  K

The volume of the container is V_c =  380mL =  380 *10^{-3}\  L

The temperature of the container is T_c  =  283 \  K

The mass of CHCl3 is m = 0.380 g

Generally the number of moles of CHCl3 present before evaporation started is mathematically represented as

n  =  \frac{m }{M }

Here M is the molar mass of CHCl3 with the value M  =  119.38 \ g/mol

=> n  =  \frac{ 0.380 }{119.38 }

=> n  =  0.00318 \  mols

Generally the number of moles of CHCl3 gas that evaporated is mathematically represented as

n_g  =  \frac{PV}{RT}

Here R is the gas constant with value R =  0.08206 L \  atm /mol\cdot  K

So

          n_g  =  \frac{0.13156* 380 *10^{-3} }{0.08206 * 283}

          n_g  =  0.00215 \  mols

Given that the number of moles of  CHCl3 evaporated is less than the number of moles of CHCl3  initially present , then it mean s that not all the liquid evaporated

At equilibrium the temperature of CHCl3 will be equal to the pressure of  air so the pressure at equilibrium is  100 mmHg

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