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dlinn [17]
3 years ago
14

100 mL of a 0.300 M solution of AgNO3 reacts with 100 mL of a 0.300 M solution of HCl in a coffee-cup calorimeter and the temper

ature rises from 21.80 °C to 23.20 °C. Assuming the density and specific heat of the resulting solution is 1.00 g/mL and 4.18 J/g ∙ °C, respectfully, what is the ΔH°rxn?
Chemistry
1 answer:
tatyana61 [14]3 years ago
7 0

Answer:

ΔH°rxn = 39013.33 J/mol = 39.013 kJ/mol.

Explanation:

  • We can calculate the amount of heat (Q) released from the solution using the relation:

<em>Q = m.c.ΔT,</em>

Where, Q is the amount of heat released from the solution (Q = ??? J).

m is the mass of the solution (m of the solution = density of the solution x volume of the solution = (1.0 g/mL)(200 mL) = 200 g.

c is the specific heat capacity of the solution (c = 4.18 J/g∙°C).

ΔT is the difference in the T (ΔT = final temperature - initial temperature = 23.20 °C - 21.80 °C = 1.4 °C).

∴ Q = m.c.ΔT = (200 g)(4.18 J/g∙°C)(1.4 °C) = 1170.4 J.

∵ ΔH°rxn = Qrxn/(no. of moles of AgNO₃).

Molarity (M) is defined as the no. of moles of solute dissolved in a 1.0 L of the solution.

M = (no. of moles of AgNO₃)/(Volume of the solution (L)).

∴ no. of moles of AgNO₃ = (M)(Volume of the solution (L)) = (0.3 M)(0.1 L) = 0.03 mol.

∴ ΔH°rxn = Qrxn/(no. of moles of AgNO₃) = (1170.4 J)/(0.03 mol) = 39013.33 J/mol = 39.013 kJ/mol.

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Answer:

3.64g

Explanation:

Given parameters:

Mass of NH₃  = 18.1g

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Unknown:

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Mass of N₂ formed  = ?

Solution:

The reaction equation is given as:

       Cu₂O + 2NH₃ → 6Cu + N₂ + 3H₂O

The limiting reactant is the one in short supply in the reaction. Let us find the number of moles of the given species;

  Number of moles = \frac{mass}{molar mass}  

Molar mass of Cu₂O = 2(63.6) + 16  = 143.2g/mol

Molar mass of NH₃  = 14 + 3(1) = 17g/mol

Number of moles of Cu₂O = \frac{18.1}{143.2}   = 0.13moles

Number of moles of NH₃   = \frac{90.4}{17}   = 5.32moles

  From this reaction;

       1 mole of  Cu₂O combines with 2 mole of NH₃

So   0.13moles of  Cu₂O will combine with 0.13 x 2 mole of NH₃

                                              = 0.26moles of NH₃

Therefore, Cu₂O is the limiting reactant. Ammonia is in excess;

Mass of N₂;

   Mass = number of moles x molar mass

    1 mole of Cu₂O  will produce 1 mole of N₂

    0.13 mole of Cu₂O  will produce 0.13 mole of N₂

    Mass  = 0.13 x (2 x 14) = 3.64g

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We know that when calculating percent yield, we use the equation:


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