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Alex73 [517]
3 years ago
15

Consider the reaction of 1-butanol with K2Cr2O7, H2SO4, heat. Draw only the organic product derived from 1-butanol.

Chemistry
1 answer:
guapka [62]3 years ago
7 0

Answer:

Butanoic acid.

Explanation:

Hello,

In this case, when a primary alcohol such as 1-butanol (OH is bonded to a primary carbon) is oxidized in the presence of a strong oxidizing media such as potassium dichromate (K2Cr2O7) and sulfuric acid, the stepwise oxidation goes to the corresponding aldehyde with a further oxidation to the corresponding carboxylic acid:

R-CH_2-OH\longrightarrow R-COH\longrightarrow R-COOH

Therefore, on the attached picture you can find that the formed aldehyde is butanal and the inly organic product, due to the strong oxidizing media is finally butanoic acid.

Best regards.

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Butane C4H10 (g),(Hf = –125.7), combusts in the presence of oxygen to form CO2 (g) (Delta.Hf = –393.5 kJ/mol), and H2O(g) (Delta
shusha [124]

Answer: The enthalpy of combustion, per mole, of butane is -2657.4 kJ

Explanation:

The balanced chemical reaction is,

2C_4H_{10}(g)+13O_2(g)\rightarrow 8CO_2(g)+10H_2O(g)

The expression for enthalpy change is,

\Delta H=[n\times H_f_{products}]-[n\times H_f_{reactants}]

Putting the values we get :

\Delta H=[8\times H_f_{CO_2}+10\times H_f_{H_2O}]-[2\times H_f_{C_4H_{10}+13\times H_f_{O_2}}]

\Delta H=[(8\times -393.5)+(10\times -241.82)]-[(2\times -125.7)+(13\times 0)]

\Delta H=-5314.8kJ

2 moles of butane releases heat = 5314.8 kJ

1 mole of butane release heat = \frac{5314.8}{2}\times 1=2657.4kJ

Thus enthalpy of combustion per mole of butane is -2657.4 kJ

3 0
3 years ago
How many moles of O2 are needed to burn 2.56 moles of CH3OH?
lukranit [14]

Answer:

n_{O_2}=3.84molO_2

Explanation:

Hello!

In this case, since the combustion reaction of methanol is:

CH_3OH+\frac{3}{2} O_2\rightarrow CO_2+2H_2O

In such a way, since there is 1:3/2 mole ratio between methanol and oxygen, we can compute the moles of oxygen that are needed to burn 2.56 moles of methanol as shown below:

n_{O_2}=2.56molCH_3OH*\frac{\frac{3}{2}molO_2}{1molCH_3OH} \\\\n_{O_2}=3.84molO_2

Best regards!

6 0
3 years ago
Which of the following is NOT true regarding Rutherford's Gold Foil experiment?
erastova [34]

Answer:

The area around the nucleus must be of low mass.

Explanation:

Rutherford`s experiment showed that there are some positive charges in the center of the atoms, and because they are all together, they will give a great mass to the atom.

It was quite different from Thomson`s experiment, in which it was thought that the negative charges were mixed with the positive charges, around the atom (like a Pudding Model). In Rutherford`s experiment, because the direction of beta particles, it was the prediction of the positive nucleus.

Hope this info is useful.

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