Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation

And

a=
b=
Now calculate V1 and V2 at given condition

Substitute given values
= 1 x 10^5 , T = 373.15 and given values of coefficients we get

Solve for V1 by iterative or alternative cubic equation solver we get

Similarly solve for state 2 at P2 = 50 bar we get

Now

a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is

a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
a. Rockwell 3. hardness
b. Instron 2. stress vs strain
c. Charpy 1. impact strength
d. Fatigue 4. Endurance Limit
e. Brinell 3. hardness
f. Izod 1. impact strength
Explanation:
Izod and Charpy are the impact strength testing procedure of a material in which a heavy hammer is attached to an arm is released to impact on the test specimen. In Izod test the specimen with v-notch is held vertical with the notch facing outward while in Charpy test the specimen is supported horizontally with notch facing inward to the impacting hammer.
Instron testing system does universal testing of the material which gradually applies the load recording all the stresses and the corresponding strains until the material fails.
Fatigue is the property of a material due to which it fails under the repeated cyclic loading by the initiation and propagation of cracks. The property of a material resist failure subjected to infinite number of repeated cyclic loads below a certain stress limit.
Rockwell and Brinell are the hardness testing methods. In Rockwell test an intender ball is firstly pressed against the specimen using minor load for a certain time and then a major load is pressed against it for a certain time. After the intender is removed the depth of impression on the surface is measured while in case of Brinell hardness we apply only one load against the intender ball for a certain time and after its removal the radius of impression is measured.
Answer:
The correct answer is 'velocity'of liquid flowing out of an orifice is proportional to the square root of the 'height' of liquid above the center of the orifice.
Explanation:
Torricelli's theorem states that

where
is the velocity with which the fluid leaves orifice
is the head under which the flow occurs.
Thus we can compare the given options to arrive at the correct answer
Velocity is proportional to square root of head under which the flow occurs.
Answer:
The amount of energy transferred to the water is 4.214 J
Explanation:
The given parameters are;
The mass of the object that drops = 5 kg
The height from which it drops = 86 mm (0.086 m)
The potential energy P.E. is given by the following formula
P.E = m·g·h
Where;
m = The mass of the object = 5 kg
g = The acceleration de to gravity = 9.8 m/s²
h = The height from which the object is dropped = 0.086 m
Therefore;
P.E. = 5 kg × 9.8 m/s² × 0.086 m = 4.214 J
Given that the potential energy is converted into heat energy, that raises the 1 g of water by 1°C, we have;
The amount of energy transferred to the water = The potential energy, P.E. = 4.214 J.